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Wikipedia

Glucal

Glucal is the glycal formed from glucose.[2] It is a chemical intermediate in the synthesis of a variety of oligosaccharides.[3]

Glucal[1]
Names
Preferred IUPAC name
(2R,3S,4R)-2-(Hydroxymethyl)-3,4-dihydro-2H-pyran-3,4-diol
Identifiers
  • 13265-84-4 Y
3D model (JSmol)
  • Interactive image
ChEMBL
  • ChEMBL2115567
ChemSpider
  • 2016480 Y
ECHA InfoCard 100.032.949
EC Number
  • 236-259-3
  • 2734736
  • DTXSID60157685
  • InChI=1S/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6+/m1/s1 Y
    Key: YVECGMZCTULTIS-PBXRRBTRSA-N Y
  • InChI=1/C6H10O4/c7-3-5-6(9)4(8)1-2-10-5/h1-2,4-9H,3H2/t4-,5-,6+/m1/s1
    Key: YVECGMZCTULTIS-PBXRRBTRBT
  • C1=CO[C@@H]([C@H]([C@@H]1O)O)CO
Properties
C6H10O4
Molar mass 146.1412
Melting point 58 to 60 °C (136 to 140 °F; 331 to 333 K)
Hazards
GHS labelling:
Warning
H315, H319, H335
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)

Glucal and its derivatives can be converted to other chemically useful sugars using the Ferrier rearrangement.

References

  1. ^ Glucal at Sigma-Aldrich
  2. ^ E.Fischer and K. Zasch. Sitzber. kgl.preuss. Akad Wiss., 16,311 (1913)
  3. ^ Seeberger, P.H., et al. Aldrichimica Acta 30, 75, (1997)


glucal, glycal, formed, from, glucose, chemical, intermediate, synthesis, variety, oligosaccharides, namespreferred, iupac, name, hydroxymethyl, dihydro, pyran, diolidentifierscas, number, 13265, model, jsmol, interactive, imagechembl, chembl2115567chemspider,. Glucal is the glycal formed from glucose 2 It is a chemical intermediate in the synthesis of a variety of oligosaccharides 3 Glucal 1 NamesPreferred IUPAC name 2R 3S 4R 2 Hydroxymethyl 3 4 dihydro 2H pyran 3 4 diolIdentifiersCAS Number 13265 84 4 Y3D model JSmol Interactive imageChEMBL ChEMBL2115567ChemSpider 2016480 YECHA InfoCard 100 032 949EC Number 236 259 3PubChem CID 2734736CompTox Dashboard EPA DTXSID60157685InChI InChI 1S C6H10O4 c7 3 5 6 9 4 8 1 2 10 5 h1 2 4 9H 3H2 t4 5 6 m1 s1 YKey YVECGMZCTULTIS PBXRRBTRSA N YInChI 1 C6H10O4 c7 3 5 6 9 4 8 1 2 10 5 h1 2 4 9H 3H2 t4 5 6 m1 s1Key YVECGMZCTULTIS PBXRRBTRBTSMILES C1 CO C H C H C H 1O O COPropertiesChemical formula C6H10O4Molar mass 146 1412Melting point 58 to 60 C 136 to 140 F 331 to 333 K HazardsGHS labelling PictogramsSignal word WarningHazard statements H315 H319 H335Precautionary statements P261 P264 P271 P280 P302 P352 P304 P340 P305 P351 P338 P312 P321 P332 P313 P337 P313 P362 P403 P233 P405 P501Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Y verify what is Y N Infobox references Glucal and its derivatives can be converted to other chemically useful sugars using the Ferrier rearrangement References Edit Glucal at Sigma Aldrich E Fischer and K Zasch Sitzber kgl preuss Akad Wiss 16 311 1913 Seeberger P H et al Aldrichimica Acta 30 75 1997 This article about an organic compound is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Glucal amp oldid 1104610431, wikipedia, wiki, book, books, library,

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