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Eudialyte group

March 14, 2024

Eudialyte group is a group of complex trigonal zircono- and, more rarely, titanosilicate minerals with general formula [N(1)N(2)N(3)N(4)N(5)]3[M(1a)M(1b)]3M(2)3M(4)Z3[Si24O72]O'4X2, where N(1) and N(2) and N(3) and N(5) = Na+ and more rarely H3O+ or H2O, N(4) = Na+, Sr2+, Mn2+ and more rarely H3O+ or H2O or K+ or Ca2+ or REE3+ (rare earth elements), M(1) and M(1b) = Ca2+, M(1a) = Ca2+ or Mn2+ or Fe2+, M(2) = Fe (both II and III), Mn and rarely Na+, K+ or Zr4+, M(3) = Si, Nb and rarely W, Ti and [] (vacancy), M(4) = Si and or rarely [], Z Zr4+ and or rarely Ti4+, and X = OH−, Cl− and more rarely CO32− or F−. Some of the eudialyte-like structures can even be more complex, however, in general, its typical feature is the presence of [Si3O9]6− and [Si9O27]18− ring silicate groups. Space group is usually R3m or R-3m but may be reduced to R3 due to cation ordering.[1] Like other zirconosilicates, the eudialyte group minerals possess alkaline ion-exchange properties, as microporous materials.[2]

List of the eudialyte-group minerals edit

Approved species edit

  • Alluaivite - Na19(Ca,Mn)6(Ti,Nb)3Si26O74Cl·2H2O (space group R-3m)
  • Andrianovite - Na12(K,Sr,Ce)3Ca6Mn3Zr3NbSi(Si3O9)2(Si9O27)2O(O,H2O,OH)5 (space group R3m)
  • Aqualite – (H3O)8(Na,K,Sr)5Ca6Zr3Si26O66(OH)9Cl (space group R3)
  • Carbokentbrooksite – (Na,[ ])12(Na,Ce)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O (space group R3m)
  • Davinciite – Na12K3Ca6Fe2+3Zr3(Si26O73OH)Cl2 (space group R3m)
  • Dualite – Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3Mn(Si51O144)(OH,H2O,Cl)9 (space group R3m)
  • Eudialyte – Na15Ca6(Fe,Mn)3Zr3(Si3O9)2SiO(Si9O27)2(O,OH,H2O)3(OH,Cl)2 (space group R-3m)
  • Feklichevite – Na11Ca9(Fe3+,Fe2+)2Zr3Nb[Si25O73](OH,H2O,Cl,O)5 (space group R3m)
  • Fengchengite – Na12[ ]3(Ca,Sr)6Fe3+3Zr3Si(Si25O73)(H2O,OH)3(OH,Cl)2 (space group R-3m)
  • Ferrokentbrooksite – Na15Ca6(Fe,Mn)3Zr3NbSi25O73(O,OH,H2O)3(Cl,F,OH)2 (space group R3m)
  • Georgbarsanovite – Na12(Mn,Sr,REE)3Ca6Fe3Zr3NbSi25O76Cl2·H2O (space group R3m)
  • Golyshevite – (Na10Ca3)Ca6Zr3Fe2SiNb(Si3O9)2(Si9O27)2(OH)3(CO3)·H2O (space group R3m)
  • Ikranite – (Na,H3O)15(Ca,Mn)6Fe3+2Zr3−4SiO(Si3O9)2(Si9O27)2·2− 3H2O (space group R3m)
  • Ilyukhinite – (H3O,Na)14Ca6Mn2Zr3Si26O72(OH)2·3H2O – the most recent add (space group R3m)[3]
  • Johnsenite-(Ce) – Na12(Ce,La,Sr,Ca)3Ca6Mn3Zr3WSiO(Si3O9)2(Si9O27)2(CO3)(OH,Cl)2·H2O (space group R3m)
  • Kentbrooksite – (Na,REE)15(Ca,REE)6(Mn,Fe)3Zr3(Si3O9)2SiO(Si9O27)2(O,OH,H2O)3F2·2H2O) (space group R3m)
  • Khomyakovite – Na12Sr3Ca6Fe3Zr3(W,Nb)SiO(Si3O9)2(Si9O27)2(O,OH,H2O)3(OH,Cl)2 (space group R3m)
  • Labyrinthite – (Na,K,Sr)35Ca12Fe3Zr6TiSi51O144(O,OH,H2O)9Cl3 (space group R3)
  • Manganokhomyakovite – Na12Sr3Ca6Mn3Zr3(W,Nb)SiO(Si3O9)2(Si9O27)2(O,OH,H2O)3(OH,Cl)2 (space group R3m)
  • Manganoeudialyte – Na14Ca6Mn3Zr3[Si26O72(OH)2]Cl2·4H2O (space group R3m)
  • Mogovidite – Na9(Ca,Na)5Ca6Zr3Fe2(SiNb)(Si3O9)2(Si9O27)2(CO3)(OH,H2O)3Cl0.3 (space group R3m)
  • Oneillite – Na15Ca3Mn3Fe2+3Zr3Nb(Si25O73)(O,OH,H2O)3(OH,Cl)2 (space group R3)
  • Raslakite – Na15Ca3Fe2+3(Na,Zr)3Zr3(Si,Nb)SiO(Si3O9)2(Si9O27)2(OH,H2O)3(Cl,OH) (space group R3)
  • Rastsvetaevite – Na27K8Ca12Fe3Zr6Si52O144(O,OH,H2O)6Cl2 (space group R3m)
  • Taseqite – Na12Sr3Ca6Fe3Zr3NbSiO(Si3O9)2(Si9O27)2(O,OH,H2O)3Cl2 (space group R3m)
  • Voronkovite – Na15(Na,Ca,Ce)3(Mn,Ca)3Fe3Zr3Si26O72(OH,O)4Cl·H2O (space group R3)
  • Zirsilite-(Ce) – (Na, [ ])12(Ce,Na)3Ca6Mn3Zr3Nb(Si25O73)(OH)3(CO3)·H2O (space group R3m)

Unnamed species edit

The list of eudialyte-related natural phases is growing. There are many such phases, some of them very complex, coded "UM" by the International Mineralogical Association, and include:[4][5]

  • UM-1971-22-SiO:CaClFeHMgMnNaNbZr – Na12Ca5(Ce,La,Y,Ca)Zr3(Zr,Nb)(Fe,Mn)3[Si9O24−26(OH)1−3]·2(Si3O9)2Cl – with variable substitution of OH for oxygen
  • UM1990-79-SiO:CaClFeHMnNaNbREEZr – Na14Ca5(Mg,Ca,Mn)Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Zr)3(Mn,Na,Ce,La,Y)(Na,H2O,K,Sr)(OH)4−5(OH,Cl) – first representative with magnesium-dominant site
  • UM1990-80- SiO:CaFeHMnNaNbREEZr – Na14Ca4(Mn,Ca)2Zr3(Si3O9)2(Si9O27)2(Si,Nb,Al,Zr)2(Fe,Mn,Al,Ti)3(Na,Ce,La,Y,Mn)(Na,H2O,K,Sr)(OH)7−8
  • UM1998-21-SiO:CaCeClHMnNaZr – Na16Ca6(Mn,Ce)3Zr3(Si3O9)2(Si9O27)2(OH,Cl)4
  • UM1999-36-SiO:CaCeHMnNaNbSrZr – Na17Mn3Ca2Zr3Si26O72(OH,F,Cl)4
  • UM2000-66-SiO:CaClFeHMnNaNbSrZr – Na12(Ca,Mn)6(Sr,Na,K)3(Fe,Mn)3(Zr,Nb)4Si25O66(OH,Cl)11
  • UM2003-39- SiO:CaClFeHHfNaNbSrTaTiZr – Na12(Na,K,Mn,Sr)2Ca5(Ca,Mn)(Zr,Hf)3(Fe,[ ],Ta)3(Si,Nb,W)(Si,Al,Ti)Si24O72(OH,O)33.5Cl·1.2H2O
  • UM2004-51-SiO:CaClFFeHNaNbTi' – Na16Ca6(Fe,Mn)3Zr3(Ti,Nb)Si26O72FCl0.5·nH2O
  • UM2006-17-SiO:CaClFFeHMnNaZr – Na15(Ca3Mn3)Zr3(Fe,Zr)3SiSi(Si3O9)2(Si9O27)2O2(OH,F,Cl)3·2H2O
  • UM2006-18-SiO:CaClFFeHMnNaZr – Na15Ca3(Mn,Fe)3Zr3(Zr,Na)3(Si,Nb)(S,Ti,Si)(Si3O9)2(Si9O27)2(O,OH)5(Cl,F,H2O) – with essential sulfur and with Zr dominant in two sites
  • UM2006-28-SiO:CaHMnNaZr – Na33Ca12Zr6Mn3(Mn,Nb,Ti)2Si50O132(O,OH)12(OH,H2O,Cl)10 – with double c unit cell dimension

In addition, there is "eudialyte 3248": Na29Ca12Zr6[Si48O132(O,OH)12]{[Na]4[Si]2{[Mn]3[Mn,Nb,Ti]2}(OH,H2O,Cl)10, plus admixtures of Ce, Sr, Ba and Y, characterized by one S-dominant site (not shown in the simplified formula)[6]

Other species edit

Rastsvetaeva et al. (2015) describe a species tentatively called "hydrorastsvetaevite", with a formula (Na11(H3O)11K6(H2O)1.5Sr)Ca12Fe3Na2MnZr6Si52O144(OH)4.5Cl3.5.[7]

Further reading edit

  • Ageeva, O. A.; Borutzky, B. Ye; Chukanov, N. V.; Sokolova, M. N. (2002). "Alluaivite and genetic aspect of the forming of enriched in Ti eudialytes in Khibiny massif". Zapiski Vserossijskogo Mineralogičeskogo Obŝestva. 131 (1): 99–106. INIST 13846139.
  • Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K.; Rozenberg, K. A. (2009). "Andrianovite, Na12(K,Sr,Ce)3Ca6Mn3Zr3Nb(Si25O73)(O, H2O,OH)5, a new potassium-rich mineral species of the eudialyte group from the Khibiny alkaline Pluton, Kola Peninsula, Russia". Geology of Ore Deposits. 50 (8): 705–12. Bibcode:2008GeoOD..50..705K. doi:10.1134/S1075701508080060. S2CID 93336238.
  • Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K. (2007). "Aqualite, a new mineral species of the eudialyte group from the Inagli alkaline pluton, Sakha-Yakutia, Russia, and the problem of oxonium in hydrated eudialytes". Geology of Ore Deposits. 49 (8): 739–51. Bibcode:2007GeoOD..49..739K. doi:10.1134/S1075701507080089. S2CID 94118983.
  • Khomyakov, A. P.; Dusmatov, V. D.; G.; Gula, A.; Ivaldi, G.; Nechelyustov, G. N. (2003). "Zapiski Vserossijskogo mineralogičeskogo obŝestva". 132 (5): 40–51. INIST 15861098. {{cite journal}}: Cite journal requires |journal= (help)
  • Khomyakov, A. P.; Nechelyustov, G. N.; Rastsvetaeva, R. K. (2007). "Dualite, Na30(Ca,Na,Ce,Sr)12(Na,Mn,Fe,Ti)6Zr3Ti3MnSi51O144(OH,H2O,Cl)9, a new zircono-titanosilicate with a modular eudialyte-like structure from Lovozero alkaline massif, Kola Peninsula, Russia". Zapiski Vserossijskogo Mineralogičeskogo Obŝestva. 136 (4): 31–42. INIST 20451408.
  • Rozenberg, K. A.; Rastsvetaeva, R. K.; Chukanov, N. V.; Verin, I. A. (2005). "Crystal structure of a niobium-deficient carbonate analogue of feklichevite". Doklady Chemistry. 400 (4–6): 25–9. doi:10.1007/s10631-005-0014-5. S2CID 95801098.
  • Rozenberg, K. A.; Rastsvetaeva, R. K.; Chukanov, N. V.; Verin, I. A. (2005). "Crystal structure of golyshevite". Crystallography Reports. 50 (4): 539–43. Bibcode:2005CryRp..50..539R. doi:10.1134/1.1996727. S2CID 95021312.
  • Johnsen, O.; Grice, J. D.; Gault, R. A. (2003). "Ferrokentbrooksite, A New Member of the Eudialyte Group from Mont Saint-Hilaire, Quebec, Canada". The Canadian Mineralogist. 41 (1): 55–60. Bibcode:2003CaMin..41...55J. doi:10.2113/gscanmin.41.1.55.
  • Piilonen, Paula C.; Locock, Andrew J.; Rowe, Ralph; Ercit, T. Scott (2007). "New Mineral Names" (PDF). American Mineralogist. 92 (4): 703–7. Bibcode:2007AmMin..92..703P. doi:10.2138/am.2007.488.
  • Chukanov, N. V.; Pekov, I. V.; Zadov, A. E.; Korovushkin, V. V.; Ekimenkova, I. A.; Rastsvetaeva, R. K. (2003). "Ikranite (Na,H3O)15(Ca,Mn,REE)6Fe3+2Zr3(□,Zr)(□,Si)Si24O66(O,OH)6Cl·nH2О and raslakite Na15Ca3Fe3(Na,Zr)3Zr3(Si,Nb)(Si25O73)(OH,H2O)3(Cl,OH) – the new eudialyte-group minerals from Lovozero massif, Kola Peninsula". Zapiski Vserossijskogo Mineralogičeskogo Obŝestva. 132 (5): 22–33. INIST 15861096.
  • Grice, Joel D.; Gault, Robert A. (2006). "Johnsenite-(Ce) : A new member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada". The Canadian Mineralogist. 44 (1): 105–15. Bibcode:2006CaMin..44..105G. doi:10.2113/gscanmin.44.1.105. INIST 17777968.
  • Jambor, John L.; Kovalenker, Vladimir A.; Roberts, Andrew C. (2000). "New Mineral Names" (PDF). American Mineralogist. 85: 873–7.
  • Khomyakov, A. P.; Nechelyustov, G. N.; Rastvetaeva, R. K. (2006). "Labyrinthite (Na,K,Sr)35Ca12Fe3Zr6TiSi51·O144(O,OH,H2O)9Cl3, a new mineral with the modular eudialyte-like structure from Khibiny alkaline massif, Kola Peninsula Russia". Zapiski Vserossijskogo Mineralogičeskogo Obŝestva. 135 (2): 38–49. INIST 18813948.
  • Ercit, T. Scott; Piilonen, Paula C.; Rowe, Ralph (2007). "New Mineral Names" (PDF). American Mineralogist. 92 (8–9): 1539–42. Bibcode:2007AmMin..92.1539E. doi:10.2138/am.2007.499.
  • Johnsen, Ole; Grice, Joel D.; Gault, Robert A. (1999). "Oneillite: a new Ca-deficient and REE-rich member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada". The Canadian Mineralogist. 37: 1295–301.
  • Khomyakov, A. P.; Nechelyustov, G. N.; Arakcheeva, A. V. (2006). "Rastsvetaevite Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]34(О,ОН,Н2О) 6Сl2, a new mineral with a modular eudialyte-like structure and crystal-chemical systematics of the eudialyte group". Zapiski Vserossijskogo Mineralogičeskogo Obŝestva. 135 (1): 49–65. INIST 18813995.
  • Petersen, O. V.; Johnsen, O.; Gault, R. A.; Niedermayr, G.; Grice, J. D. (2004). "Taseqite, a new member of the eudialyte group from the Ilímaussaq alkaline complex, South Greenland". Neues Jahrbuch für Mineralogie – Monatshefte. 2004 (2): 83–96. doi:10.1127/0028-3649/2004/2004-0083. INIST 15422915.
  • Rastsvetaeva, R. K.; Chukanov, N. V.; Zaitsev, V. A.; Aksenov, S. M.; Viktorova, K. A. (2018–05). "Crystal Structure of Cl-Deficient Analogue of Taseqite from Odikhincha Massif". Crystallography Reports. 63 (3): 349–357. doi:10.1134/s1063774518030240. ISSN 1063-7745

References edit

  1. ^ Johnsen, O.; Ferraris, G.; Gault, R. A.; Grice, J. D.; Kampf, A. R.; Pekov, I. V. (2003). "The Nomenclature of Eudialyte-Group Minerals". The Canadian Mineralogist. 41 (3): 785–794. Bibcode:2003CaMin..41..785J. doi:10.2113/gscanmin.41.3.785.
  2. ^ Zubkova, Natalia V.; Pushcharovsky, Dmitrii Yu. (2008). Mixed-Framework Microporous Natural Zirconosilicates : Minerals as Advanced Materials I. pp. 45–56. doi:10.1007/978-3-540-77123-4_6. ISBN 978-3-540-77122-7.
  3. ^ Hålenius, U.; Hatert, F.; Pasero, M.; Mills, S. J. (2015). "New minerals and nomenclature modifications approved in 2015". Mineralogical Magazine. 79 (7): 1859–1864. Bibcode:2015MinM...79.1859H. doi:10.1180/minmag.2015.079.7.18.
  4. ^ Mindat, http://www.mindat.org
  5. ^ Smith, D.G.W., and Nickel, E.H.N., 2007. A System of Codification for Unnamed Minerals: Report of the SubCommittee for Unnamed Minerals of the IMA Commission on New Minerals, Nomenclature and Classification. Canadian Mineralogist v. 45, p.983-1055; http://nrmima.nrm.se/Valid2012.pdf
  6. ^ Rastsvetaeva, R. K.; Ivanova, A. G.; Khomyakov, A. P. (2006-10-01). "Modular structure of hypermanganese eudialyte". Doklady Earth Sciences. 410 (1): 1075–1079. doi:10.1134/S1028334X06070166. ISSN 1531-8354.
  7. ^ Rastsvetaeva, R. K.; Aksenov, S. M.; Rozenberg, K. A. (2015). "Crystal structure and genesis of the hydrated analog of rastsvetaevite". Crystallography Reports. 60 (6): 831–840. Bibcode:2015CryRp..60..831R. doi:10.1134/S1063774515060279. S2CID 97600291.

External links edit

  • Mindat.org
  • The Eudialyte homepage

March 14, 2024
eudialyte, group, this, article, includes, list, general, references, lacks, sufficient, corresponding, inline, citations, please, help, improve, this, article, introducing, more, precise, citations, january, 2014, learn, when, remove, this, template, message,. This article includes a list of general references but it lacks sufficient corresponding inline citations Please help to improve this article by introducing more precise citations January 2014 Learn how and when to remove this template message Eudialyte group is a group of complex trigonal zircono and more rarely titanosilicate minerals with general formula N 1 N 2 N 3 N 4 N 5 3 M 1a M 1b 3M 2 3M 4 Z3 Si24O72 O 4X2 where N 1 and N 2 and N 3 and N 5 Na and more rarely H3O or H2O N 4 Na Sr2 Mn2 and more rarely H3O or H2O or K or Ca2 or REE3 rare earth elements M 1 and M 1b Ca2 M 1a Ca2 or Mn2 or Fe2 M 2 Fe both II and III Mn and rarely Na K or Zr4 M 3 Si Nb and rarely W Ti and vacancy M 4 Si and or rarely Z Zr4 and or rarely Ti4 and X OH Cl and more rarely CO32 or F Some of the eudialyte like structures can even be more complex however in general its typical feature is the presence of Si3O9 6 and Si9O27 18 ring silicate groups Space group is usually R3m or R 3m but may be reduced to R3 due to cation ordering 1 Like other zirconosilicates the eudialyte group minerals possess alkaline ion exchange properties as microporous materials 2 Contents 1 List of the eudialyte group minerals 1 1 Approved species 1 2 Unnamed species 1 3 Other species 2 Further reading 3 References 4 External linksList of the eudialyte group minerals editApproved species edit Alluaivite Na19 Ca Mn 6 Ti Nb 3Si26O74Cl 2H2O space group R 3m Andrianovite Na12 K Sr Ce 3Ca6Mn3Zr3NbSi Si3O9 2 Si9O27 2O O H2O OH 5 space group R3m Aqualite H3O 8 Na K Sr 5Ca6Zr3Si26O66 OH 9Cl space group R3 Carbokentbrooksite Na 12 Na Ce 3Ca6Mn3Zr3Nb Si25O73 OH 3 CO3 H2O space group R3m Davinciite Na12K3Ca6Fe2 3 Zr3 Si26O73OH Cl2 space group R3m Dualite Na30 Ca Na Ce Sr 12 Na Mn Fe Ti 6Zr3Ti3Mn Si51O144 OH H2O Cl 9 space group R3m Eudialyte Na15Ca6 Fe Mn 3Zr3 Si3O9 2SiO Si9O27 2 O OH H2O 3 OH Cl 2 space group R 3m Feklichevite Na11Ca9 Fe3 Fe2 2Zr3Nb Si25O73 OH H2O Cl O 5 space group R3m Fengchengite Na12 3 Ca Sr 6Fe3 3 Zr3Si Si25O73 H2O OH 3 OH Cl 2 space group R 3m Ferrokentbrooksite Na15Ca6 Fe Mn 3Zr3NbSi25O73 O OH H2O 3 Cl F OH 2 space group R3m Georgbarsanovite Na12 Mn Sr REE 3Ca6Fe3Zr3NbSi25O76Cl2 H2O space group R3m Golyshevite Na10Ca3 Ca6Zr3Fe2SiNb Si3O9 2 Si9O27 2 OH 3 CO3 H2O space group R3m Ikranite Na H3O 15 Ca Mn 6Fe3 2Zr3 4SiO Si3O9 2 Si9O27 2 2 3H2O space group R3m Ilyukhinite H3O Na 14Ca6Mn2Zr3Si26O72 OH 2 3H2O the most recent add space group R3m 3 Johnsenite Ce Na12 Ce La Sr Ca 3Ca6Mn3Zr3WSiO Si3O9 2 Si9O27 2 CO3 OH Cl 2 H2O space group R3m Kentbrooksite Na REE 15 Ca REE 6 Mn Fe 3Zr3 Si3O9 2SiO Si9O27 2 O OH H2O 3F2 2H2O space group R3m Khomyakovite Na12Sr3Ca6Fe3Zr3 W Nb SiO Si3O9 2 Si9O27 2 O OH H2O 3 OH Cl 2 space group R3m Labyrinthite Na K Sr 35Ca12Fe3Zr6TiSi51O144 O OH H2O 9Cl3 space group R3 Manganokhomyakovite Na12Sr3Ca6Mn3Zr3 W Nb SiO Si3O9 2 Si9O27 2 O OH H2O 3 OH Cl 2 space group R3m Manganoeudialyte Na14Ca6Mn3Zr3 Si26O72 OH 2 Cl2 4H2O space group R3m Mogovidite Na9 Ca Na 5Ca6Zr3Fe2 SiNb Si3O9 2 Si9O27 2 CO3 OH H2O 3Cl0 3 space group R3m Oneillite Na15Ca3Mn3Fe2 3Zr3Nb Si25O73 O OH H2O 3 OH Cl 2 space group R3 Raslakite Na15Ca3Fe2 3 Na Zr 3Zr3 Si Nb SiO Si3O9 2 Si9O27 2 OH H2O 3 Cl OH space group R3 Rastsvetaevite Na27K8Ca12Fe3Zr6Si52O144 O OH H2O 6Cl2 space group R3m Taseqite Na12Sr3Ca6Fe3Zr3NbSiO Si3O9 2 Si9O27 2 O OH H2O 3Cl2 space group R3m Voronkovite Na15 Na Ca Ce 3 Mn Ca 3Fe3Zr3Si26O72 OH O 4Cl H2O space group R3 Zirsilite Ce Na 12 Ce Na 3Ca6Mn3Zr3Nb Si25O73 OH 3 CO3 H2O space group R3m Unnamed species edit The list of eudialyte related natural phases is growing There are many such phases some of them very complex coded UM by the International Mineralogical Association and include 4 5 UM 1971 22 SiO CaClFeHMgMnNaNbZr Na12Ca5 Ce La Y Ca Zr3 Zr Nb Fe Mn 3 Si9O24 26 OH 1 3 2 Si3O9 2Cl with variable substitution of OH for oxygen UM1990 79 SiO CaClFeHMnNaNbREEZr Na14Ca5 Mg Ca Mn Zr3 Si3O9 2 Si9O27 2 Si Nb Al Zr 2 Fe Zr 3 Mn Na Ce La Y Na H2O K Sr OH 4 5 OH Cl first representative with magnesium dominant site UM1990 80 SiO CaFeHMnNaNbREEZr Na14Ca4 Mn Ca 2Zr3 Si3O9 2 Si9O27 2 Si Nb Al Zr 2 Fe Mn Al Ti 3 Na Ce La Y Mn Na H2O K Sr OH 7 8 UM1998 21 SiO CaCeClHMnNaZr Na16Ca6 Mn Ce 3Zr3 Si3O9 2 Si9O27 2 OH Cl 4 UM1999 36 SiO CaCeHMnNaNbSrZr Na17Mn3Ca2Zr3Si26O72 OH F Cl 4 UM2000 66 SiO CaClFeHMnNaNbSrZr Na12 Ca Mn 6 Sr Na K 3 Fe Mn 3 Zr Nb 4Si25O66 OH Cl 11 UM2003 39 SiO CaClFeHHfNaNbSrTaTiZr Na12 Na K Mn Sr 2Ca5 Ca Mn Zr Hf 3 Fe Ta 3 Si Nb W Si Al Ti Si24O72 OH O 33 5Cl 1 2H2O UM2004 51 SiO CaClFFeHNaNbTi Na16Ca6 Fe Mn 3Zr3 Ti Nb Si26O72FCl0 5 nH2O UM2006 17 SiO CaClFFeHMnNaZr Na15 Ca3Mn3 Zr3 Fe Zr 3SiSi Si3O9 2 Si9O27 2O2 OH F Cl 3 2H2O UM2006 18 SiO CaClFFeHMnNaZr Na15Ca3 Mn Fe 3Zr3 Zr Na 3 Si Nb S Ti Si Si3O9 2 Si9O27 2 O OH 5 Cl F H2O with essential sulfur and with Zr dominant in two sites UM2006 28 SiO CaHMnNaZr Na33Ca12Zr6Mn3 Mn Nb Ti 2Si50O132 O OH 12 OH H2O Cl 10 with double c unit cell dimensionIn addition there is eudialyte 3248 Na29Ca12Zr6 Si48O132 O OH 12 Na 4 Si 2 Mn 3 Mn Nb Ti 2 OH H2O Cl 10 plus admixtures of Ce Sr Ba and Y characterized by one S dominant site not shown in the simplified formula 6 Other species edit Rastsvetaeva et al 2015 describe a species tentatively called hydrorastsvetaevite with a formula Na11 H3O 11K6 H2O 1 5Sr Ca12Fe3Na2MnZr6Si52O144 OH 4 5Cl3 5 7 Further reading editAgeeva O A Borutzky B Ye Chukanov N V Sokolova M N 2002 Alluaivite and genetic aspect of the forming of enriched in Ti eudialytes in Khibiny massif Zapiski Vserossijskogo Mineralogiceskogo Obŝestva 131 1 99 106 INIST 13846139 Khomyakov A P Nechelyustov G N Rastsvetaeva R K Rozenberg K A 2009 Andrianovite Na12 K Sr Ce 3Ca6Mn3Zr3Nb Si25O73 O H2O OH 5 a new potassium rich mineral species of the eudialyte group from the Khibiny alkaline Pluton Kola Peninsula Russia Geology of Ore Deposits 50 8 705 12 Bibcode 2008GeoOD 50 705K doi 10 1134 S1075701508080060 S2CID 93336238 Khomyakov A P Nechelyustov G N Rastsvetaeva R K 2007 Aqualite a new mineral species of the eudialyte group from the Inagli alkaline pluton Sakha Yakutia Russia and the problem of oxonium in hydrated eudialytes Geology of Ore Deposits 49 8 739 51 Bibcode 2007GeoOD 49 739K doi 10 1134 S1075701507080089 S2CID 94118983 Khomyakov A P Dusmatov V D G Gula A Ivaldi G Nechelyustov G N 2003 Zapiski Vserossijskogo mineralogiceskogo obŝestva 132 5 40 51 INIST 15861098 a href Template Cite journal html title Template Cite journal cite journal a Cite journal requires journal help Khomyakov A P Nechelyustov G N Rastsvetaeva R K 2007 Dualite Na30 Ca Na Ce Sr 12 Na Mn Fe Ti 6Zr3Ti3MnSi51O144 OH H2O Cl 9 a new zircono titanosilicate with a modular eudialyte like structure from Lovozero alkaline massif Kola Peninsula Russia Zapiski Vserossijskogo Mineralogiceskogo Obŝestva 136 4 31 42 INIST 20451408 Rozenberg K A Rastsvetaeva R K Chukanov N V Verin I A 2005 Crystal structure of a niobium deficient carbonate analogue of feklichevite Doklady Chemistry 400 4 6 25 9 doi 10 1007 s10631 005 0014 5 S2CID 95801098 Rozenberg K A Rastsvetaeva R K Chukanov N V Verin I A 2005 Crystal structure of golyshevite Crystallography Reports 50 4 539 43 Bibcode 2005CryRp 50 539R doi 10 1134 1 1996727 S2CID 95021312 Johnsen O Grice J D Gault R A 2003 Ferrokentbrooksite A New Member of the Eudialyte Group from Mont Saint Hilaire Quebec Canada The Canadian Mineralogist 41 1 55 60 Bibcode 2003CaMin 41 55J doi 10 2113 gscanmin 41 1 55 Piilonen Paula C Locock Andrew J Rowe Ralph Ercit T Scott 2007 New Mineral Names PDF American Mineralogist 92 4 703 7 Bibcode 2007AmMin 92 703P doi 10 2138 am 2007 488 Chukanov N V Pekov I V Zadov A E Korovushkin V V Ekimenkova I A Rastsvetaeva R K 2003 Ikranite Na H3O 15 Ca Mn REE 6Fe3 2Zr3 Zr Si Si24O66 O OH 6Cl nH2O and raslakite Na15Ca3Fe3 Na Zr 3Zr3 Si Nb Si25O73 OH H2O 3 Cl OH the new eudialyte group minerals from Lovozero massif Kola Peninsula Zapiski Vserossijskogo Mineralogiceskogo Obŝestva 132 5 22 33 INIST 15861096 Grice Joel D Gault Robert A 2006 Johnsenite Ce A new member of the eudialyte group from Mont Saint Hilaire Quebec Canada The Canadian Mineralogist 44 1 105 15 Bibcode 2006CaMin 44 105G doi 10 2113 gscanmin 44 1 105 INIST 17777968 Jambor John L Kovalenker Vladimir A Roberts Andrew C 2000 New Mineral Names PDF American Mineralogist 85 873 7 Khomyakov A P Nechelyustov G N Rastvetaeva R K 2006 Labyrinthite Na K Sr 35Ca12Fe3Zr6TiSi51 O144 O OH H2O 9Cl3 a new mineral with the modular eudialyte like structure from Khibiny alkaline massif Kola Peninsula Russia Zapiski Vserossijskogo Mineralogiceskogo Obŝestva 135 2 38 49 INIST 18813948 Ercit T Scott Piilonen Paula C Rowe Ralph 2007 New Mineral Names PDF American Mineralogist 92 8 9 1539 42 Bibcode 2007AmMin 92 1539E doi 10 2138 am 2007 499 Johnsen Ole Grice Joel D Gault Robert A 1999 Oneillite a new Ca deficient and REE rich member of the eudialyte group from Mont Saint Hilaire Quebec Canada The Canadian Mineralogist 37 1295 301 Khomyakov A P Nechelyustov G N Arakcheeva A V 2006 Rastsvetaevite Na27K8Ca12Fe3Zr6Si4 Si3O9 4 Si9O27 34 O ON N2O 6Sl2 a new mineral with a modular eudialyte like structure and crystal chemical systematics of the eudialyte group Zapiski Vserossijskogo Mineralogiceskogo Obŝestva 135 1 49 65 INIST 18813995 Petersen O V Johnsen O Gault R A Niedermayr G Grice J D 2004 Taseqite a new member of the eudialyte group from the Ilimaussaq alkaline complex South Greenland Neues Jahrbuch fur Mineralogie Monatshefte 2004 2 83 96 doi 10 1127 0028 3649 2004 2004 0083 INIST 15422915 Rastsvetaeva R K Chukanov N V Zaitsev V A Aksenov S M Viktorova K A 2018 05 Crystal Structure of Cl Deficient Analogue of Taseqite from Odikhincha Massif Crystallography Reports 63 3 349 357 doi 10 1134 s1063774518030240 ISSN 1063 7745References edit Johnsen O Ferraris G Gault R A Grice J D Kampf A R Pekov I V 2003 The Nomenclature of Eudialyte Group Minerals The Canadian Mineralogist 41 3 785 794 Bibcode 2003CaMin 41 785J doi 10 2113 gscanmin 41 3 785 Zubkova Natalia V Pushcharovsky Dmitrii Yu 2008 Mixed Framework Microporous Natural Zirconosilicates Minerals as Advanced Materials I pp 45 56 doi 10 1007 978 3 540 77123 4 6 ISBN 978 3 540 77122 7 Halenius U Hatert F Pasero M Mills S J 2015 New minerals and nomenclature modifications approved in 2015 Mineralogical Magazine 79 7 1859 1864 Bibcode 2015MinM 79 1859H doi 10 1180 minmag 2015 079 7 18 Mindat http www mindat org Smith D G W and Nickel E H N 2007 A System of Codification for Unnamed Minerals Report of the SubCommittee for Unnamed Minerals of the IMA Commission on New Minerals Nomenclature and Classification Canadian Mineralogist v 45 p 983 1055 http nrmima nrm se Valid2012 pdf Rastsvetaeva R K Ivanova A G Khomyakov A P 2006 10 01 Modular structure of hypermanganese eudialyte Doklady Earth Sciences 410 1 1075 1079 doi 10 1134 S1028334X06070166 ISSN 1531 8354 Rastsvetaeva R K Aksenov S M Rozenberg K A 2015 Crystal structure and genesis of the hydrated analog of rastsvetaevite Crystallography Reports 60 6 831 840 Bibcode 2015CryRp 60 831R doi 10 1134 S1063774515060279 S2CID 97600291 External links editMindat org The Eudialyte homepage Retrieved from https en wikipedia org w index php title Eudialyte group amp oldid 1196953840, wikipedia, wiki, book, books, library,

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