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2-Chloropropylene

2-Chloropropylene is an organochlorine compound with the formula CH2=C(Cl)CH3. It is a colorless gas that condenses just below room temperature. Unlike the closely related vinyl chloride, which is a major industrial chemical, 2-chloropropene has no commercial applications and is a lightly studied compound. In the research laboratory, it is used as a source of the 2-propenyl group.[1] One early synthesis involves dehydrohalogenation of 1,2-dichloropropane with potassium hydroxide.[2]

2-Chloropropylene
Names
Other names
2-chloropropene
Identifiers
  • 557-98-2 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 10730
ECHA InfoCard 100.008.353
EC Number
  • 209-187-5
  • 11203
UNII
  • 50TXN55E4A
UN number 2456
  • DTXSID4040262
  • InChI=1S/C3H5Cl/c1-3(2)4/h1H2,2H3
    Key: PNLQPWWBHXMFCA-UHFFFAOYSA-N
  • CC(=C)Cl
Properties
C3H5Cl
Molar mass 76.52 g·mol−1
Appearance colorless gas
Density 0.9017 g/mL (20 °C)
Melting point −137.4 °C (−215.3 °F; 135.8 K)
Boiling point 22.6 °C (72.7 °F; 295.8 K)
Hazards
GHS labelling:
Danger
H224, H302, H312, H315, H319, H332, H335
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P312, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P370+P378, P403+P233, P403+P235, P405, P501
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

References Edit

  1. ^ Takahashi, Tamotsu; Kotora, Martin; Fischer, Reinald; Nishihara, Yasushi; Nakajima, Kiyohiko (1995). "Oxidative Addition of 2-Haloalkene to Zirconocene". Journal of the American Chemical Society. 117 (44): 11039–11040. doi:10.1021/ja00149a040.
  2. ^ Goudet, Henry; Schenker, Fritz (1927). "Recherches sur quelques dérivés du propylène". Helvetica Chimica Acta. 10: 132–140. doi:10.1002/hlca.19270100117. hdl:2027/uc1.b2617289.

chloropropylene, organochlorine, compound, with, formula, colorless, that, condenses, just, below, room, temperature, unlike, closely, related, vinyl, chloride, which, major, industrial, chemical, chloropropene, commercial, applications, lightly, studied, comp. 2 Chloropropylene is an organochlorine compound with the formula CH2 C Cl CH3 It is a colorless gas that condenses just below room temperature Unlike the closely related vinyl chloride which is a major industrial chemical 2 chloropropene has no commercial applications and is a lightly studied compound In the research laboratory it is used as a source of the 2 propenyl group 1 One early synthesis involves dehydrohalogenation of 1 2 dichloropropane with potassium hydroxide 2 2 Chloropropylene NamesOther names 2 chloropropeneIdentifiersCAS Number 557 98 2 Y3D model JSmol Interactive imageChemSpider 10730ECHA InfoCard 100 008 353EC Number 209 187 5PubChem CID 11203UNII 50TXN55E4AUN number 2456CompTox Dashboard EPA DTXSID4040262InChI InChI 1S C3H5Cl c1 3 2 4 h1H2 2H3Key PNLQPWWBHXMFCA UHFFFAOYSA NSMILES CC C ClPropertiesChemical formula C 3H 5ClMolar mass 76 52 g mol 1Appearance colorless gasDensity 0 9017 g mL 20 C Melting point 137 4 C 215 3 F 135 8 K Boiling point 22 6 C 72 7 F 295 8 K HazardsGHS labelling PictogramsSignal word DangerHazard statements H224 H302 H312 H315 H319 H332 H335Precautionary statements P210 P233 P240 P241 P242 P243 P261 P264 P270 P271 P280 P301 P312 P302 P352 P303 P361 P353 P304 P312 P304 P340 P305 P351 P338 P312 P321 P322 P330 P332 P313 P337 P313 P362 P363 P370 P378 P403 P233 P403 P235 P405 P501Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesReferences Edit Takahashi Tamotsu Kotora Martin Fischer Reinald Nishihara Yasushi Nakajima Kiyohiko 1995 Oxidative Addition of 2 Haloalkene to Zirconocene Journal of the American Chemical Society 117 44 11039 11040 doi 10 1021 ja00149a040 Goudet Henry Schenker Fritz 1927 Recherches sur quelques derives du propylene Helvetica Chimica Acta 10 132 140 doi 10 1002 hlca 19270100117 hdl 2027 uc1 b2617289 Retrieved from https en wikipedia org w index php title 2 Chloropropylene amp oldid 1142640225, wikipedia, wiki, book, books, library,

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