1,3-Dioxetane (1,3-dioxacyclobutane) is a heterocyclicorganic compound with formula C2O2H4, whose backbone is a four-member ring of alternating oxygen and carbon atoms. It can be viewed as a dimer of formaldehyde (COH2).
Derivatives of 1,3-dioxetane are rarely encountered as intermediates in the literature. Usually, they are prepared via [2+2] cycloadditions of two carbonyl compounds. Molecular orbital theory calculations suggest that they should be more stable than the 1,2-isomers, which are more intensively studied.[1]
^Cordier, C.; Leach, S.; Nelson, A. (2014). Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 29: Acetals: Hal/X and O/O, S, Se, Te. Georg Thieme Verlag. p. 407. ISBN9783131720412.
dioxetane, dioxacyclobutane, heterocyclic, organic, compound, with, formula, c2o2h4, whose, backbone, four, member, ring, alternating, oxygen, carbon, atoms, viewed, dimer, formaldehyde, coh2, namespreferred, iupac, name, systematic, iupac, name, dioxacyclobut. 1 3 Dioxetane 1 3 dioxacyclobutane is a heterocyclic organic compound with formula C2O2H4 whose backbone is a four member ring of alternating oxygen and carbon atoms It can be viewed as a dimer of formaldehyde COH2 1 3 Dioxetane NamesPreferred IUPAC name 1 3 DioxetaneSystematic IUPAC name 1 3 DioxacyclobutaneIdentifiersCAS Number 287 50 3 N3D model JSmol Interactive imageInteractive imageChemSpider 126850 YPubChem CID 143777CompTox Dashboard EPA DTXSID40210146InChI InChI 1S C2H4O2 c1 3 2 4 1 h1 2H2 YKey GFAJOMHUNNCCJQ UHFFFAOYSA N YInChI 1 C2H4O2 c1 3 2 4 1 h1 2H2Key GFAJOMHUNNCCJQ UHFFFAOYATSMILES C1OCO1O1COC1PropertiesChemical formula C 2H 4O 2Molar mass 60 052 g mol 1Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references Derivatives of 1 3 dioxetane are rarely encountered as intermediates in the literature Usually they are prepared via 2 2 cycloadditions of two carbonyl compounds Molecular orbital theory calculations suggest that they should be more stable than the 1 2 isomers which are more intensively studied 1 See also edit1 2 DioxetaneReferences edit Cordier C Leach S Nelson A 2014 Science of Synthesis Houben Weyl Methods of Molecular Transformations Vol 29 Acetals Hal X and O O S Se Te Georg Thieme Verlag p 407 ISBN 9783131720412 nbsp This article about a heterocyclic compound is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title 1 3 Dioxetane amp oldid 1076886211, wikipedia, wiki, book, books, library,
