The structure of the cation consists of a three-bladed propeller structure with a planar amine. It is nearly identical to the parent triphenylamine. The weakly coordinating anion is SbCl− 6, which is octahedral.[3]
^Earle, Martyn J.; Vibert, Aude; Jahn, Ullrich (2011). "Tris(4-bromophenyl)aminium Hexachloroantimonate". Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289X.rt397.pub2. ISBN978-0-471-93623-7.
^Connelly, N. G.; Geiger, W. E. (1996). "Chemical Redox Agents for Organometallic Chemistry". Chem. Rev.96 (2): 877–910. doi:10.1021/cr940053x. PMID 11848774.
^ Quiroz-Guzman, Mauricio; Brown, Seth N. (2010). "Tris(4-bromophenyl)aminium hexachloridoantimonate ('Magic Blue'): A strong oxidant with low inner-sphere reorganization". Acta Crystallographica Section C. 66 (7): m171–m173. Bibcode:2010AcCrC..66M.171Q. doi:10.1107/S0108270110019748. PMID 20603548.{{cite journal}}: CS1 maint: multiple names: authors list (link)
tris, bromophenyl, ammoniumyl, hexachloroantimonate, organic, compound, with, formula, brc6h4, sbcl6, commonly, known, magic, blue, hexachloroantimonate, salt, amine, radical, cation, blue, solid, that, reacts, with, many, solvents, soluble, acetonitrile, comp. Tris 4 bromophenyl ammoniumyl hexachloroantimonate is the organic compound with the formula 4 BrC6H4 3N SbCl6 1 Commonly known as magic blue it is the hexachloroantimonate salt of an amine radical cation It is a blue solid that reacts with many solvents but is soluble in acetonitrile The compound is a popular oxidizing agent in organic and organometallic chemistry with a reduction potential of 0 67 V versus ferrocene ferrocenium acetonitrile solution or 0 70 V versus ferrocene ferrocenium dichloromethane solution 2 Tris 4 bromophenyl ammoniumyl hexachloroantimonate Identifiers CAS Number 24964 91 8 salt37881 41 7 cation 3D model JSmol Interactive image ChemSpider 21493919 PubChem CID 16688313 InChI InChI 1S C18H12Br3N 6ClH Sb c19 13 1 7 16 8 2 13 22 17 9 3 14 20 4 10 17 18 11 5 15 21 6 12 18 h1 12H 6 1H q 1 5 p 6Key SDHBPVANTRLAKE UHFFFAOYSA H SMILES C1 CC CC C1 N C2 CC C C C2 Br C3 CC C C C3 Br Br Cl Sb Cl Cl Cl Cl Cl Properties Chemical formula p BrC6H4 3N SbCl6 Molar mass 816 47 g mol 1 Appearance blue solid Melting point 141 to 142 C 286 to 288 F 414 to 415 K Solubility in water acetonitrile Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references The structure of the cation consists of a three bladed propeller structure with a planar amine It is nearly identical to the parent triphenylamine The weakly coordinating anion is SbCl 6 which is octahedral 3 Related compounds editMagic green tris 2 4 dibromophenyl ammoniumyl hexachloroantimonate 4 References edit Earle Martyn J Vibert Aude Jahn Ullrich 2011 Tris 4 bromophenyl aminium Hexachloroantimonate Encyclopedia of Reagents for Organic Synthesis doi 10 1002 047084289X rt397 pub2 ISBN 978 0 471 93623 7 Connelly N G Geiger W E 1996 Chemical Redox Agents for Organometallic Chemistry Chem Rev 96 2 877 910 doi 10 1021 cr940053x PMID 11848774 Quiroz Guzman Mauricio Brown Seth N 2010 Tris 4 bromophenyl aminium hexachloridoantimonate Magic Blue A strong oxidant with low inner sphere reorganization Acta Crystallographica Section C 66 7 m171 m173 Bibcode 2010AcCrC 66M 171Q doi 10 1107 S0108270110019748 PMID 20603548 a href Template Cite journal html title Template Cite journal cite journal a CS1 maint multiple names authors list link Schmidt Werner Steckhan Eberhard 1980 Uber organische Elektronenubertragersysteme I Elektrochemische und spektroskopische Untersuchung bromsubstituierter Triarylamin Redoxsysteme Chemische Berichte 113 2 577 585 doi 10 1002 cber 19801130215 Retrieved from https en wikipedia org w index php title Tris 4 bromophenyl ammoniumyl hexachloroantimonate amp oldid 1211205370, wikipedia, wiki, book, books, library,
