Potassium tetracarbonyliron hydride is the inorganic salt with the formula K[HFe(CO)4]. A pale yellow solid, it is the potassium salt of [HFe(CO)4]−, which is the conjugate base of iron tetracarbonyl dihydride:[1][2]
^Brunet, Jean-Jacques (1998). "Coordination Chemistry of Mononuclear Iron Carbonyl Complexes". Coordination Chemistry Reviews. 178–180: 331–351. doi:10.1016/S0010-8545(98)00075-7.
^Brunet, J.J. (1990). "Tetracarbonylhydridoferrates, MHFe(CO)4: Versatile tools in Organic Synthesis and Catalysis". Chem. Rev.90 (6): 1041–1059. doi:10.1021/cr00104a006.
^Brunet, J.-J.; Kindela, F. B.; Neibecker, D. (1992). "Trans-Tricarbonylbis(Phosphine)Iron(0) Complexes: One-Pot Syntheses from Pentacarbonyliron". trans-Tricarbonylbis(Phosphine)Iron(0) Complexes: One-Pot Syntheses from Pentacarbonyliron. Inorganic Syntheses. Vol. 29. pp. 151–156. doi:10.1002/9780470132609.ch36. ISBN9780470132609.
^Brunet, J.-J.; Kindela, F. B.; Neibecker (1996). "One-Pot Synthesis of Dicarbonyltris(Phosphane)Iron(0) Complexes from Pentacarbonyliron". Inorganic Syntheses. Inorganic Syntheses. Vol. 31. pp. 202–210. doi:10.1002/9780470132623.ch30. ISBN9780470132623.
April 21, 2023
potassium, tetracarbonyliron, hydride, inorganic, salt, with, formula, pale, yellow, solid, potassium, salt, which, conjugate, base, iron, tetracarbonyl, dihydride, namesother, names, potassium, tetracarbonylhydroferrate, identifierscas, number, 17857, model, . Potassium tetracarbonyliron hydride is the inorganic salt with the formula K HFe CO 4 A pale yellow solid it is the potassium salt of HFe CO 4 which is the conjugate base of iron tetracarbonyl dihydride 1 2 Potassium tetracarbonyliron hydride NamesOther names potassium tetracarbonylhydroferrate 1 IdentifiersCAS Number 17857 24 83D model JSmol Interactive imagePubChem CID 13932590InChI InChI 1S 4CO Fe K H c4 1 2 q 1 1 Key ZCWNHXZCHBPQAK UHFFFAOYSA NSMILES C O C O C O C O K Fe H PropertiesChemical formula C 4H Fe K O 4Molar mass 207 991 g mol 1Appearance yellow solidExcept where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox references H2Fe CO 4 KOH K HFe CO 4 H2OPotassium tetracarbonyliron hydride is prepared by treating iron pentacarbonyl with potassium hydroxide 3 Fe CO 5 2 KOH K HFe CO 4 KHCO3Potassium tetracarbonyliron hydride is an intermediate in the synthesis of trisubstituted phosphine complexes 4 K HFe CO 4 3 PBu3 EtOH Fe CO 2 PBu3 3 EtOK 2 CO H2References Edit Brunet Jean Jacques 1998 Coordination Chemistry of Mononuclear Iron Carbonyl Complexes Coordination Chemistry Reviews 178 180 331 351 doi 10 1016 S0010 8545 98 00075 7 Brunet J J 1990 Tetracarbonylhydridoferrates MHFe CO 4 Versatile tools in Organic Synthesis and Catalysis Chem Rev 90 6 1041 1059 doi 10 1021 cr00104a006 Brunet J J Kindela F B Neibecker D 1992 Trans Tricarbonylbis Phosphine Iron 0 Complexes One Pot Syntheses from Pentacarbonyliron trans Tricarbonylbis Phosphine Iron 0 Complexes One Pot Syntheses from Pentacarbonyliron Inorganic Syntheses Vol 29 pp 151 156 doi 10 1002 9780470132609 ch36 ISBN 9780470132609 Brunet J J Kindela F B Neibecker 1996 One Pot Synthesis of Dicarbonyltris Phosphane Iron 0 Complexes from Pentacarbonyliron Inorganic Syntheses Inorganic Syntheses Vol 31 pp 202 210 doi 10 1002 9780470132623 ch30 ISBN 9780470132623 Retrieved from https en wikipedia org w index php title Potassium tetracarbonyliron hydride amp oldid 1059728985, wikipedia, wiki, book, books, library,
