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Peter T. Wolczanski

Peter Thomas Wolczanski is the George W. and Grace L. Todd professor of Chemistry at Cornell University.

Peter T. Wolczanski
BornAugust 28, 1954 (1954-08-28) (age 69)
Alma materMassachusetts Institute of Technology
California Institute of Technology
Known forLow-valent three-coordinate transition metal complexes
Small molecule activation (most notably complete CO scission)
Scientific career
FieldsInorganic and Organometallic Chemistry
InstitutionsCornell University
ThesisThe reactivity and syntheses of mono and bis permethylcyclopentadienyl zirconium hydrides (1981)
Doctoral advisorJohn E. Bercaw
Other academic advisorsMark Wrighton
Notable studentsChristopher C. Cummins
Websitewolczanski.chem.cornell.edu/pete/

Education edit

Wolczanski obtained his B.S. in Chemistry at the Massachusetts Institute of Technology in 1976 while doing research under the direction of Mark Wrighton. He entered graduate school at the California Institute of Technology, working under John Bercaw on various chemistries of permethylzirconocene hydrides and was awarded a doctorate degree in 1981.[1]

Awards and Professional Activities edit

  • Fellow, American Academy of Arts and Sciences (1999)
  • Casimir Funk Natural Science Award, Polish Institute of Arts & Sciences of America (1998)
  • Alfred P. Sloan Foundation Fellow (1987-1989)
  • J. S. Fluor Fellow (1980)
  • 2011 ACS Award in Organometallic Chemistry
  • Fellow, American Academy of Arts and Sciences (1999)
  • Casimir Funk Natural Science Award, Polish Institute of Arts & Sciences of America (1998
  • Dow Chemical Co., Technical Advisory Boards (1996-2003 (Synthesis), 2006-2007
  • Visiting Miller Research Professorship, Univ. California, Berkeley (1995)
  • Fellow, Alfred P. Sloan Foundation (1987-1989
  • Union Carbide Innovation Recognition Program (1988
  • Chair, Organometallic Subdivision, ACS Division of Inorganic Chemistry (1994-1995)
  • Executive Committee, ACS Division of Inorganic Chemistry (1991-1993)

Selected publications edit

  • "Carbon Monoxide Cleavage by (silox)3Ta (silox = tBu3SiO-): Physical, Theoretical and Mechanistic Investigations." Neithamer, D.R.; LaPointe, R.E.; Wheeler, R.A.; Richeson, D.S.; Van Duyne, G.D.; Wolczanski, P.T. J. Am. Chem. Soc. 1989, 111, 9056-9072.
  • "Symmetry and Geometry Considerations of Atom Transfer: Deoxygenation of (silox)3WNO and R3PO (R = Me, Ph, tBu) by (silox)3M (M = V, NbL (L = PMe3, 4-picoline), Ta; silox = tBu3SiO)." Veige, A. S.; Slaughter, L. M.; Lobkovsky, E. B.; Wolczanski, P. T.; Matsunaga, N.; Decker, S. A.; Cundari, T. R. Inorg. Chem. 2003, 42, 6204-6224.
  • "Thermodynamics, Kinetics and Mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) Rearrangements (silox = tBu3SiO; M = Nb, Ta)." Hirsekorn, K. F.; Veige, A. S.; Marshak, M. P.; Koldobskaya, Y.; Wolczanski, P. T.; Cundari, T. R.; Lobkovsky, E. B. J. Am. Chem. Soc. 2005, 127, 4809-4830.
  • "3-Center-4-Electron Bonding in [(silox)2Mo=NR]2(µ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum π-Bond Energy Estimate." Rosenfeld, D. C.; Wolczanski, P. T.; Barakat, K. A.; Buda, C.; Cundari, T. R. J. Am. Chem. Soc. 2005, 127, 8262-8263.
  • "PC Bond Cleavage of (silox)3NbPMe3 (silox = tBu3SiO) under Dihydrogen Leads to (silox)3Nb=CH2, (silox)3Nb=PH or (silox)3NbP(H)Nb(silox)3, and CH4." Hirsekorn, K. F.; Veige, A. S.; Wolczanski, P. T. J. Am. Chem. Soc. 2006, 128, 2192-2193.

References edit

  1. ^ Wolczanski, Peter Thomas (1981). The reactivity and syntheses of mono and bis permethylcyclopentadienyl zirconium hydrides (Ph.D.). California Institute of Technology. OCLC 437056692 – via ProQuest.

External links edit

  • Wolczanski Group Website

peter, wolczanski, peter, thomas, wolczanski, george, grace, todd, professor, chemistry, cornell, university, bornaugust, 1954, 1954, utica, nyalma, matermassachusetts, institute, technologycalifornia, institute, technologyknown, forlow, valent, three, coordin. Peter Thomas Wolczanski is the George W and Grace L Todd professor of Chemistry at Cornell University Peter T WolczanskiBornAugust 28 1954 1954 08 28 age 69 Utica NYAlma materMassachusetts Institute of TechnologyCalifornia Institute of TechnologyKnown forLow valent three coordinate transition metal complexesSmall molecule activation most notably complete CO scission Scientific careerFieldsInorganic and Organometallic ChemistryInstitutionsCornell UniversityThesisThe reactivity and syntheses of mono and bis permethylcyclopentadienyl zirconium hydrides 1981 Doctoral advisorJohn E BercawOther academic advisorsMark WrightonNotable studentsChristopher C CumminsWebsitewolczanski wbr chem wbr cornell wbr edu wbr pete wbr Contents 1 Education 2 Awards and Professional Activities 3 Selected publications 4 References 5 External linksEducation editWolczanski obtained his B S in Chemistry at the Massachusetts Institute of Technology in 1976 while doing research under the direction of Mark Wrighton He entered graduate school at the California Institute of Technology working under John Bercaw on various chemistries of permethylzirconocene hydrides and was awarded a doctorate degree in 1981 1 Awards and Professional Activities editFellow American Academy of Arts and Sciences 1999 Casimir Funk Natural Science Award Polish Institute of Arts amp Sciences of America 1998 Alfred P Sloan Foundation Fellow 1987 1989 J S Fluor Fellow 1980 2011 ACS Award in Organometallic Chemistry Fellow American Academy of Arts and Sciences 1999 Casimir Funk Natural Science Award Polish Institute of Arts amp Sciences of America 1998 Dow Chemical Co Technical Advisory Boards 1996 2003 Synthesis 2006 2007 Visiting Miller Research Professorship Univ California Berkeley 1995 Fellow Alfred P Sloan Foundation 1987 1989 Union Carbide Innovation Recognition Program 1988 Chair Organometallic Subdivision ACS Division of Inorganic Chemistry 1994 1995 Executive Committee ACS Division of Inorganic Chemistry 1991 1993 Selected publications edit Carbon Monoxide Cleavage by silox 3Ta silox tBu3SiO Physical Theoretical and Mechanistic Investigations Neithamer D R LaPointe R E Wheeler R A Richeson D S Van Duyne G D Wolczanski P T J Am Chem Soc 1989 111 9056 9072 Symmetry and Geometry Considerations of Atom Transfer Deoxygenation of silox 3WNO and R3PO R Me Ph tBu by silox 3M M V NbL L PMe3 4 picoline Ta silox tBu3SiO Veige A S Slaughter L M Lobkovsky E B Wolczanski P T Matsunaga N Decker S A Cundari T R Inorg Chem 2003 42 6204 6224 Thermodynamics Kinetics and Mechanism of silox 3M olefin to silox 3M alkylidene Rearrangements silox tBu3SiO M Nb Ta Hirsekorn K F Veige A S Marshak M P Koldobskaya Y Wolczanski P T Cundari T R Lobkovsky E B J Am Chem Soc 2005 127 4809 4830 3 Center 4 Electron Bonding in silox 2Mo NR 2 µ Hg Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum p Bond Energy Estimate Rosenfeld D C Wolczanski P T Barakat K A Buda C Cundari T R J Am Chem Soc 2005 127 8262 8263 PC Bond Cleavage of silox 3NbPMe3 silox tBu3SiO under Dihydrogen Leads to silox 3Nb CH2 silox 3Nb PH or silox 3NbP H Nb silox 3 and CH4 Hirsekorn K F Veige A S Wolczanski P T J Am Chem Soc 2006 128 2192 2193 References edit Wolczanski Peter Thomas 1981 The reactivity and syntheses of mono and bis permethylcyclopentadienyl zirconium hydrides Ph D California Institute of Technology OCLC 437056692 via ProQuest External links editWolczanski Group Website Retrieved from https en wikipedia org w index php title Peter T Wolczanski amp oldid 1149909630, wikipedia, wiki, book, books, library,

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