fbpx
Wikipedia

Methylenecyclohexane

Methylenecyclohexane (IUPAC name: methylidenecyclohexane) is an organic compound with the molecular formula C7H12.

Methylenecyclohexane
Names
Preferred IUPAC name
Methylidenecyclohexane
Other names
Methylenecyclohexane
Identifiers
  • 1192-37-6 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 13846 Y
ECHA InfoCard 100.013.412
EC Number
  • 214-752-4
  • 14502
UNII
  • ET4NT9H9LB Y
  • DTXSID4061595
  • InChI=1S/C7H12/c1-7-5-3-2-4-6-7/h1-6H2 Y
    Key: YULMNMJFAZWLLN-UHFFFAOYSA-N Y
  • InChI=1/C7H12/c1-7-5-3-2-4-6-7/h1-6H2
    Key: YULMNMJFAZWLLN-UHFFFAOYAJ
  • C=C1CCCCC1
Properties
C7H12
Molar mass 96.170 g/mol
Boiling point 102 to 103 °C (216 to 217 °F; 375 to 376 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Y verify (what is YN ?)

Synthesis edit

It can be produced by a Wittig reaction or a reaction with a Tebbe's reagent from cyclohexanone.[1][2][3] It can also be synthesized as a side product of the dehydration of 2-methylcyclohexanol into 1-methylcyclohexene.

Structure edit

Methylenecyclohexane is an unsaturated hydrocarbon, containing a cyclohexane ring with a methylene (methylidine) group attached.

See also edit

References edit

  1. ^ Wittig, George; Schoellkopf, U. (1960). "Methylenecyclohexane". Organic Syntheses. 40: 66. doi:10.15227/orgsyn.040.0066.
  2. ^ Mark, Herman F. (2007). Encyclopedia of Polymer Science and Technology, Concise. Hoboken, New Jersey: John Wiley & Sons. p. 682. ISBN 978-0-470-04610-4. I this way, cyclohexanone is transformed into methylenecyclohexene and benzaldehyde into stryene.
  3. ^ Dalton, David R. (August 4, 2011). Foundations of Organic Chemistry: Unity and Diversity of Structures, Pathways, and Reactions. John Wiley & Sons. pp. 819–820. ISBN 978-1-118-00538-5. Now, when cyclohexanone is added to the solution in which the [Tebbe] reagent has been generated, reaction occurs to produce methylenecyclohexane and triphenylphosphine oxide

methylenecyclohexane, iupac, name, methylidenecyclohexane, organic, compound, with, molecular, formula, c7h12, namespreferred, iupac, name, methylidenecyclohexaneother, names, identifierscas, number, 1192, model, jsmol, interactive, imagechemspider, 13846, yec. Methylenecyclohexane IUPAC name methylidenecyclohexane is an organic compound with the molecular formula C7H12 Methylenecyclohexane NamesPreferred IUPAC name MethylidenecyclohexaneOther names MethylenecyclohexaneIdentifiersCAS Number 1192 37 6 Y3D model JSmol Interactive imageChemSpider 13846 YECHA InfoCard 100 013 412EC Number 214 752 4PubChem CID 14502UNII ET4NT9H9LB YCompTox Dashboard EPA DTXSID4061595InChI InChI 1S C7H12 c1 7 5 3 2 4 6 7 h1 6H2 YKey YULMNMJFAZWLLN UHFFFAOYSA N YInChI 1 C7H12 c1 7 5 3 2 4 6 7 h1 6H2Key YULMNMJFAZWLLN UHFFFAOYAJSMILES C C1CCCCC1PropertiesChemical formula C7H12Molar mass 96 170 g molBoiling point 102 to 103 C 216 to 217 F 375 to 376 K Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Y verify what is Y N Infobox references Contents 1 Synthesis 2 Structure 3 See also 4 ReferencesSynthesis editIt can be produced by a Wittig reaction or a reaction with a Tebbe s reagent from cyclohexanone 1 2 3 It can also be synthesized as a side product of the dehydration of 2 methylcyclohexanol into 1 methylcyclohexene Structure editMethylenecyclohexane is an unsaturated hydrocarbon containing a cyclohexane ring with a methylene methylidine group attached See also editMethylcyclohexane MethylenecyclopropaneReferences edit Wittig George Schoellkopf U 1960 Methylenecyclohexane Organic Syntheses 40 66 doi 10 15227 orgsyn 040 0066 Mark Herman F 2007 Encyclopedia of Polymer Science and Technology Concise Hoboken New Jersey John Wiley amp Sons p 682 ISBN 978 0 470 04610 4 I this way cyclohexanone is transformed into methylenecyclohexene and benzaldehyde into stryene Dalton David R August 4 2011 Foundations of Organic Chemistry Unity and Diversity of Structures Pathways and Reactions John Wiley amp Sons pp 819 820 ISBN 978 1 118 00538 5 Now when cyclohexanone is added to the solution in which the Tebbe reagent has been generated reaction occurs to produce methylenecyclohexane and triphenylphosphine oxide Retrieved from https en wikipedia org w index php title Methylenecyclohexane amp oldid 1111372084, wikipedia, wiki, book, books, library,

article

, read, download, free, free download, mp3, video, mp4, 3gp, jpg, jpeg, gif, png, picture, music, song, movie, book, game, games.