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Landfill gas

February 15, 2024

Landfill gas is a mix of different gases created by the action of microorganisms within a landfill as they decompose organic waste, including for example, food waste and paper waste. Landfill gas is approximately forty to sixty percent methane, with the remainder being mostly carbon dioxide. Trace amounts of other volatile organic compounds (VOCs) comprise the remainder (<1%). These trace gases include a large array of species, mainly simple hydrocarbons.[1]

A gas flare produced by a landfill in Lake County, Ohio

Landfill gases have an influence on climate change. The major components are CO2 and methane, both of which are greenhouse gases. Methane in the atmosphere is a far more potent greenhouse gas, with each molecule having twenty-five times the effect of a molecule of carbon dioxide. Methane itself however accounts for less composition of the atmosphere than does carbon dioxide. Landfills are the third-largest source of methane in the US.[2]

Because of the significant negative effects of these gases, regulatory regimes have been set up to monitor landfill gas, reduce the amount of biodegradable content in municipal waste, and to create landfill gas utilization strategies, which include gas flaring or capture for electricity generation.

Production edit

Landfill gases are the result of three processes:[1]

  1. evaporation of volatile organic compounds (e.g., solvents)
  2. chemical reactions between waste components
  3. microbial action, especially methanogenesis.

The first two depend strongly on the nature of the waste. The dominant process in most landfills is the third process whereby anaerobic bacteria decompose organic waste to produce biogas, which consists of methane and carbon dioxide together with traces of other compounds.[3] Despite the heterogeneity of waste, the evolution of gases follows well defined kinetic pattern. Formation of methane and CO2 commences about six months after depositing the landfill material. The evolution of gas reaches a maximum at about 20 years, then declines over the course of decades.[1]

Conditions and changes within the landfill can be observed with electrical resistivity tomography (ERT) to detect sources of landfill gas,[4] and leachate movements and pathways.[5] Conditions at different locations, such as temperature, moisture levels and fraction of biodegradable material can be inferred and this information can be used to improve gas production with optimal well locations over hotspots and interventions such as heap irrigation.

When landfill gas permeates through a soil cover, a fraction of the methane in the gas is oxidized microbially to CO2.[6]

Monitoring edit

Main article: Landfill gas monitoring

Because gases produced by landfills are both valuable and sometimes hazardous, monitoring techniques have been developed. Flame ionization detectors can be used to measure methane levels as well as total VOC levels. Surface monitoring and sub-surface monitoring as well as monitoring of the ambient air is carried out. In the U.S., under the Clean Air Act of 1990, it is required that many large landfills install gas collection and control systems, which means that at the very least the facilities must collect and flare the gas.

U.S. Federal regulations under Subtitle D of RCRA formed in October 1979 regulate the siting, design, construction, operation, monitoring, and closure of MSW landfills. Subtitle D now requires controls on the migration of methane in landfill gas. Monitoring requirements must be met at landfills during their operation, and for an additional 30 years after. The landfills affected by Subtitle D of RCRA are required to control gas by establishing a way to check for methane emissions periodically and therefore prevent off-site migration. Landfill owners and operators must make sure the concentration of methane gas does not exceed 25% of the LEL for methane in the facilities' structures and the LEL for methane at the facility boundary.[7]

Use edit

 
Landfill gas collection system
 
Leachate evaporation system
Main article: Landfill gas utilization

The gases produced within a landfill can be collected and used in various ways. The landfill gas can be utilized directly on-site by a boiler or any type of combustion system, providing heat. Electricity can also be generated on-site through the use of microturbines, steam turbines, or fuel cells.[8] The landfill gas can also be sold off-site and sent into natural gas pipelines. This approach requires the gas to be processed into pipeline quality, e.g., by removing various contaminants and components.[9] Landfill gas can also be used to evaporate leachate, another byproduct of the landfill process. This application displaces another fuel that was previously used for the same thing.[10]

The efficiency of gas collection at landfills directly impacts the amount of energy that can be recovered - closed landfills (those no longer accepting waste) collect gas more efficiently than open landfills (those that are still accepting waste). A comparison of collection efficiency at closed and open landfills found about a 17 percentage point difference between the two.[11]

Opposition edit

Capture and use of landfill gas can be expensive. Some environmental groups claim that the projects do not produce "renewable power" because trash (their source) is not renewable. The Sierra Club opposes government subsidies for such projects.[12] The Natural Resources Defense Council (NRDC) argues that government incentives should be directed more towards solar, wind, and energy-efficiency efforts.[12]

Safety edit

Landfill gas emissions can lead to environmental, hygiene and security problems in the landfill.[13][14] Several accidents have occurred, for example at Loscoe, England in 1986,[15] where migrating landfill gas accumulated and partially destroyed a property. An accident causing two deaths occurred from an explosion in a house adjacent to Skellingsted landfill in Denmark in 1991.[16] Due to the risk presented by landfill gas, there is a clear need to monitor gas produced by landfills. In addition to the risk of fire and explosion, gas migration in the subsurface can result in contact with landfill gas with groundwater. This, in turn, can result in contamination of groundwater by organic compounds present in nearly all landfill gas.[17]

Although usually evolved only in trace amounts, landfills do release some aromatics and chlorocarbons.

Landfill gas migration, due to pressure differentials and diffusion, can occur. This can create an explosion hazard if the gas reaches sufficiently high concentrations in adjacent buildings.

By country edit

Brazil edit

This section is an excerpt from Landfill gas emission reduction in Brazil.[edit]
Brazil has established a strong public policy using Clean Development Mechanism Projects to reduce methane emissions from landfills. An important component of these projects is the sale of avoided emissions by the private market to generate revenue.

United States edit

This section is an excerpt from Landfills in the United States § Landfill gas utilization.[edit]
 
JFK Presidential Library and Museum - category 3 landfill post-closure site

A United States Environmental Protection Agency (EPA) report indicates that as of 2016, counts of operational municipal solid waste landfills range between 1,900 and 2,000. In a nationwide study done by the Environmental Research and Education Foundation in 2013, only 1,540 operational municipal solid waste landfills were counted throughout the United States. Decomposing waste in these landfills produces landfill gas, which is a mixture of about half methane and half carbon dioxide. Landfills are the third-largest source of methane emissions in the United States, with municipal solid waste landfills representing 95 percent of this fraction.[18][19]

In the U.S., the number of landfill gas projects increased from 399 in 2005, to 594 in 2012[20] according to the Environmental Protection Agency. These projects are popular because they control energy costs and reduce greenhouse gas emissions. These projects collect the methane gas and treat it, so it can be used for electricity or upgraded to pipeline-grade gas. (Methane gas has twenty-one times the global warming potential of carbon dioxide).[21] For example, in the U.S., Waste Management uses landfill gas as an energy source at 110 landfill gas-to-energy facilities. This energy production offsets almost two million tons of coal per year, creating energy equivalent to that needed by four hundred thousand homes. These projects also reduce greenhouse gas emissions into the atmosphere.[22]

The EPA, which estimates that hundreds of landfills could support gas to energy projects, has also established the Landfill Methane Outreach Program. This program was developed to reduce methane emissions from landfills in a cost-effective manner by encouraging the development of environmentally and economically beneficial landfill gas-to-energy projects.[23]

See also edit

References edit

  1. ^ a b c Hans-Jürgen Ehrig, Hans-Joachim Schneider and Volkmar Gossow "Waste, 7. Deposition" in Ullmann's Encyclopedia of Industrial Chemistry, 2011, Wiley-VCH, Weinheim. doi:10.1002/14356007.o28_o07
  2. ^ "Methane Emissions". Environmental Protection Agency. 23 December 2015. Retrieved 13 June 2016.
  3. ^ "Landfill Gas and Biogas". U.S. Energy Information Administration. Retrieved 2015-11-22.
  4. ^ Deep Scan Tech (2022): Deep Scan Tech supports Ukraine in improving its energy independence.
  5. ^ Deep Scan Tech (2022): Deep Scan Tech helps landfills protect the environment with a demonstration project in Ukraine.
  6. ^ Scheutz, C., Kjeldsen, P., Bogner, J.E., De Visscher, A., Gebert, J., Hilger, H.A. & Spokas, K. (2009) Microbial methane oxidation processes and technologies for mitigation of landfill gas emissions. Waste Manage. Res. 27:409-455.
  7. ^ "Landfill Gas Control Measures". Agency for Toxic Substances & Disease Registry. Retrieved 2010-04-26.
  8. ^ Sullivan, Patrick. "The Importance of Landfill Gas Capture and Utilization in the U.S" (PDF). SUR. Retrieved 27 September 2013.
  9. ^ "Landfill Gas Power Plants". California Energy Commission. Retrieved 27 September 2013.
  10. ^ "Landfill Methane Outreach program". EPA. Retrieved 27 September 2013.
  11. ^ Powell, Jon T.; Townsend, Timothy G.; Zimmerman, Julie B. (2015-09-21). "Estimates of solid waste disposal rates and reduction targets for landfill gas emissions". Nature Climate Change. advance online publication (2): 162–165. doi:10.1038/nclimate2804. ISSN 1758-6798.
  12. ^ a b Koch, Wendy (2010-02-25). "Landfill Projects on the rise". USA Today. Retrieved 2010-04-25.
  13. ^ Brosseau, J. (1994) Trace gas compound emissions from municipal landfill sanitary sites; Atmospheric-Environment 28 (2), 285-293
  14. ^ Christensen, T. H., Cossu, R. & Stegmann, R. (1999) Landfilling of waste: Biogas
  15. ^ Williams and Aitkenhead (1991) Lessons from Loscoe: The uncontrolled migration of landfill gas; The Quarterly Journal of Engineering Geology 24 (2), 191-207
  16. ^ . mst.dk (in Danish). Archived from the original on July 22, 2011.
  17. ^ Kerfoot, H.B., Chapter 3.5 In Christensen, T. H., Cossu, R. & Stegmann, R. (1999)Landfilling of waste: Biogas
  18. ^ EPA,OAR,OAP,CCD, US (15 April 2016). "Basic Information about Landfill Gas - US EPA". US EPA.{{cite web}}: CS1 maint: multiple names: authors list (link)
  19. ^ "Inventory of US Greenhouse Gas Emissions and Sinks, 1990-2015" (PDF). United States Environmental Protection Agency. 2017. Retrieved 2022-04-04.
  20. ^ "Landfill Gas to Energy". EPA. Retrieved 2012-07-29.
  21. ^ Koch, Wendy (2010-02-25). "Landfill Projects on the rise". USA Today. Retrieved 2010-04-25.
  22. ^ "Landfill Gas to Energy". Waste Management. Retrieved 2010-04-26.
  23. ^ . Gas Separation Technology LLC. Archived from the original on 2017-05-06. Retrieved 2010-04-26.

External links edit

  • GA Mansoori, N Enayati, LB Agyarko (2016), Energy: Sources, Utilization, Legislation, Sustainability, Illinois as Model State, World Sci. Pub. Co., ISBN 978-981-4704-00-7
  • "Primer on Landfill Gas as "Green Energy"". Energy Justice Network. Retrieved 2010-04-25.
  • Koch, Wendy (2010-02-25). "Landfill Projects on the rise". USA Today. Retrieved 2010-04-25.
  • "Landfill Gas to Energy". Waste Management. Retrieved 2010-04-26.
  • . Gas Separation Technology LLC. Archived from the original on 2017-05-06. Retrieved 2010-04-26.
  • "Landfill Gas Control Measures". Agency for Toxic Substances & Disease Registry. Retrieved 2010-04-26.

February 15, 2024
landfill, different, gases, created, action, microorganisms, within, landfill, they, decompose, organic, waste, including, example, food, waste, paper, waste, approximately, forty, sixty, percent, methane, with, remainder, being, mostly, carbon, dioxide, trace. Landfill gas is a mix of different gases created by the action of microorganisms within a landfill as they decompose organic waste including for example food waste and paper waste Landfill gas is approximately forty to sixty percent methane with the remainder being mostly carbon dioxide Trace amounts of other volatile organic compounds VOCs comprise the remainder lt 1 These trace gases include a large array of species mainly simple hydrocarbons 1 A gas flare produced by a landfill in Lake County OhioLandfill gases have an influence on climate change The major components are CO2 and methane both of which are greenhouse gases Methane in the atmosphere is a far more potent greenhouse gas with each molecule having twenty five times the effect of a molecule of carbon dioxide Methane itself however accounts for less composition of the atmosphere than does carbon dioxide Landfills are the third largest source of methane in the US 2 Because of the significant negative effects of these gases regulatory regimes have been set up to monitor landfill gas reduce the amount of biodegradable content in municipal waste and to create landfill gas utilization strategies which include gas flaring or capture for electricity generation Contents 1 Production 2 Monitoring 3 Use 3 1 Opposition 4 Safety 5 By country 5 1 Brazil 5 2 United States 6 See also 7 References 8 External linksProduction editLandfill gases are the result of three processes 1 evaporation of volatile organic compounds e g solvents chemical reactions between waste components microbial action especially methanogenesis The first two depend strongly on the nature of the waste The dominant process in most landfills is the third process whereby anaerobic bacteria decompose organic waste to produce biogas which consists of methane and carbon dioxide together with traces of other compounds 3 Despite the heterogeneity of waste the evolution of gases follows well defined kinetic pattern Formation of methane and CO2 commences about six months after depositing the landfill material The evolution of gas reaches a maximum at about 20 years then declines over the course of decades 1 Conditions and changes within the landfill can be observed with electrical resistivity tomography ERT to detect sources of landfill gas 4 and leachate movements and pathways 5 Conditions at different locations such as temperature moisture levels and fraction of biodegradable material can be inferred and this information can be used to improve gas production with optimal well locations over hotspots and interventions such as heap irrigation When landfill gas permeates through a soil cover a fraction of the methane in the gas is oxidized microbially to CO2 6 Monitoring editMain article Landfill gas monitoring Because gases produced by landfills are both valuable and sometimes hazardous monitoring techniques have been developed Flame ionization detectors can be used to measure methane levels as well as total VOC levels Surface monitoring and sub surface monitoring as well as monitoring of the ambient air is carried out In the U S under the Clean Air Act of 1990 it is required that many large landfills install gas collection and control systems which means that at the very least the facilities must collect and flare the gas U S Federal regulations under Subtitle D of RCRA formed in October 1979 regulate the siting design construction operation monitoring and closure of MSW landfills Subtitle D now requires controls on the migration of methane in landfill gas Monitoring requirements must be met at landfills during their operation and for an additional 30 years after The landfills affected by Subtitle D of RCRA are required to control gas by establishing a way to check for methane emissions periodically and therefore prevent off site migration Landfill owners and operators must make sure the concentration of methane gas does not exceed 25 of the LEL for methane in the facilities structures and the LEL for methane at the facility boundary 7 Use edit nbsp Landfill gas collection system nbsp Leachate evaporation systemMain article Landfill gas utilization The gases produced within a landfill can be collected and used in various ways The landfill gas can be utilized directly on site by a boiler or any type of combustion system providing heat Electricity can also be generated on site through the use of microturbines steam turbines or fuel cells 8 The landfill gas can also be sold off site and sent into natural gas pipelines This approach requires the gas to be processed into pipeline quality e g by removing various contaminants and components 9 Landfill gas can also be used to evaporate leachate another byproduct of the landfill process This application displaces another fuel that was previously used for the same thing 10 The efficiency of gas collection at landfills directly impacts the amount of energy that can be recovered closed landfills those no longer accepting waste collect gas more efficiently than open landfills those that are still accepting waste A comparison of collection efficiency at closed and open landfills found about a 17 percentage point difference between the two 11 Opposition edit Capture and use of landfill gas can be expensive Some environmental groups claim that the projects do not produce renewable power because trash their source is not renewable The Sierra Club opposes government subsidies for such projects 12 The Natural Resources Defense Council NRDC argues that government incentives should be directed more towards solar wind and energy efficiency efforts 12 Safety editLandfill gas emissions can lead to environmental hygiene and security problems in the landfill 13 14 Several accidents have occurred for example at Loscoe England in 1986 15 where migrating landfill gas accumulated and partially destroyed a property An accident causing two deaths occurred from an explosion in a house adjacent to Skellingsted landfill in Denmark in 1991 16 Due to the risk presented by landfill gas there is a clear need to monitor gas produced by landfills In addition to the risk of fire and explosion gas migration in the subsurface can result in contact with landfill gas with groundwater This in turn can result in contamination of groundwater by organic compounds present in nearly all landfill gas 17 Although usually evolved only in trace amounts landfills do release some aromatics and chlorocarbons Landfill gas migration due to pressure differentials and diffusion can occur This can create an explosion hazard if the gas reaches sufficiently high concentrations in adjacent buildings By country editBrazil edit This section is an excerpt from Landfill gas emission reduction in Brazil edit Brazil has established a strong public policy using Clean Development Mechanism Projects to reduce methane emissions from landfills An important component of these projects is the sale of avoided emissions by the private market to generate revenue United States edit This section is an excerpt from Landfills in the United States Landfill gas utilization edit nbsp JFK Presidential Library and Museum category 3 landfill post closure siteA United States Environmental Protection Agency EPA report indicates that as of 2016 counts of operational municipal solid waste landfills range between 1 900 and 2 000 In a nationwide study done by the Environmental Research and Education Foundation in 2013 only 1 540 operational municipal solid waste landfills were counted throughout the United States Decomposing waste in these landfills produces landfill gas which is a mixture of about half methane and half carbon dioxide Landfills are the third largest source of methane emissions in the United States with municipal solid waste landfills representing 95 percent of this fraction 18 19 In the U S the number of landfill gas projects increased from 399 in 2005 to 594 in 2012 20 according to the Environmental Protection Agency These projects are popular because they control energy costs and reduce greenhouse gas emissions These projects collect the methane gas and treat it so it can be used for electricity or upgraded to pipeline grade gas Methane gas has twenty one times the global warming potential of carbon dioxide 21 For example in the U S Waste Management uses landfill gas as an energy source at 110 landfill gas to energy facilities This energy production offsets almost two million tons of coal per year creating energy equivalent to that needed by four hundred thousand homes These projects also reduce greenhouse gas emissions into the atmosphere 22 The EPA which estimates that hundreds of landfills could support gas to energy projects has also established the Landfill Methane Outreach Program This program was developed to reduce methane emissions from landfills in a cost effective manner by encouraging the development of environmentally and economically beneficial landfill gas to energy projects 23 See also edit nbsp Biology portal nbsp Technology portal nbsp Environment portal nbsp Renewable energy portalAnaerobic digestion Biodegradability Biogas Flue gas Landfill gas utilization Relative cost of electricity generated by different sources Underground coal gasificationReferences edit a b c Hans Jurgen Ehrig Hans Joachim Schneider and Volkmar Gossow Waste 7 Deposition in Ullmann s Encyclopedia of Industrial Chemistry 2011 Wiley VCH Weinheim doi 10 1002 14356007 o28 o07 Methane Emissions Environmental Protection Agency 23 December 2015 Retrieved 13 June 2016 Landfill Gas and Biogas U S Energy Information Administration Retrieved 2015 11 22 Deep Scan Tech 2022 Deep Scan Tech supports Ukraine in improving its energy independence Deep Scan Tech 2022 Deep Scan Tech helps landfills protect the environment with a demonstration project in Ukraine Scheutz C Kjeldsen P Bogner J E De Visscher A Gebert J Hilger H A amp Spokas K 2009 Microbial methane oxidation processes and technologies for mitigation of landfill gas emissions Waste Manage Res 27 409 455 Landfill Gas Control Measures Agency for Toxic Substances amp Disease Registry Retrieved 2010 04 26 Sullivan Patrick The Importance of Landfill Gas Capture and Utilization in the U S PDF SUR Retrieved 27 September 2013 Landfill Gas Power Plants California Energy Commission Retrieved 27 September 2013 Landfill Methane Outreach program EPA Retrieved 27 September 2013 Powell Jon T Townsend Timothy G Zimmerman Julie B 2015 09 21 Estimates of solid waste disposal rates and reduction targets for landfill gas emissions Nature Climate Change advance online publication 2 162 165 doi 10 1038 nclimate2804 ISSN 1758 6798 a b Koch Wendy 2010 02 25 Landfill Projects on the rise USA Today Retrieved 2010 04 25 Brosseau J 1994 Trace gas compound emissions from municipal landfill sanitary sites Atmospheric Environment 28 2 285 293 Christensen T H Cossu R amp Stegmann R 1999 Landfilling of waste Biogas Williams and Aitkenhead 1991 Lessons from Loscoe The uncontrolled migration of landfill gas The Quarterly Journal of Engineering Geology 24 2 191 207 Danish EPA mst dk in Danish Archived from the original on July 22 2011 Kerfoot H B Chapter 3 5 In Christensen T H Cossu R amp Stegmann R 1999 Landfilling of waste Biogas EPA OAR OAP CCD US 15 April 2016 Basic Information about Landfill Gas US EPA US EPA a href Template Cite web html title Template Cite web cite web a CS1 maint multiple names authors list link Inventory of US Greenhouse Gas Emissions and Sinks 1990 2015 PDF United States Environmental Protection Agency 2017 Retrieved 2022 04 04 Landfill Gas to Energy EPA Retrieved 2012 07 29 Koch Wendy 2010 02 25 Landfill Projects on the rise USA Today Retrieved 2010 04 25 Landfill Gas to Energy Waste Management Retrieved 2010 04 26 Landfill Gas Gas Separation Technology LLC Archived from the original on 2017 05 06 Retrieved 2010 04 26 External links editGA Mansoori N Enayati LB Agyarko 2016 Energy Sources Utilization Legislation Sustainability Illinois as Model State World Sci Pub Co ISBN 978 981 4704 00 7 Primer on Landfill Gas as Green Energy Energy Justice Network Retrieved 2010 04 25 Koch Wendy 2010 02 25 Landfill Projects on the rise USA Today Retrieved 2010 04 25 Landfill Gas to Energy Waste Management Retrieved 2010 04 26 Landfill Gas Gas Separation Technology LLC Archived from the original on 2017 05 06 Retrieved 2010 04 26 Landfill Gas Control Measures Agency for Toxic Substances amp Disease Registry Retrieved 2010 04 26 Retrieved from https en wikipedia org w index php title Landfill gas amp oldid 1204185563, wikipedia, wiki, book, books, library,

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