Foam glass

Foam glass is a porous glass foam material. Its advantages as a building material include its light weight, high strength, and thermal and acoustic insulating properties. It is made by heating a mixture of crushed or granulated glass and a blowing agent (chemical foaming agent) such as carbon or limestone. Near the melting point of the glass, the blowing agent releases a gas, producing a foaming effect in the glass. After cooling the mixture hardens into a rigid material with gas-filled closed-cell pores comprising a large portion of its volume.

Block of foam glass

As to chemical foaming agents, there are several additives that facilitate the release of the gaseous phase upon heat treatment.^[1][2][3][4] In general, these additives are categorized into two categories: a) redox and neutralization agents, and b) decomposing agents. Redox and neutralization agents include nonoxide materials, e.g. carbides or nitrides. Decomposing agents include sulfates, e.g. CaSO₄•nH₂O,^{[citation needed]} organic compounds, and carbonates, e.g. CaCO₃. These materials release gas following decomposition and/or burning.

History

In the 1930s, Saint-Gobain of France first developed foam glass with calcium carbonate as a foaming agent. In 1932, it applied for a patent.^[5]

An early report of foam glass as a construction material was made by the Soviet scientist, Professor Isaak Ilych Kitaygorodskiy (ru) at the All-Union Conference on Standardization and Manufacture of New Construction Materials in Moscow in 1932.^[6] Subsequently, in 1939, the Soviet Union reports experimentally produced foam glass at the intermediate pilot plant of the Mendeleev Institute of Chemical Technology. A glass powder screened through a 0.09 mm mesh was mixed with limestone and later on with anthracite and coal as gasifier.^[7]

The product that is known today as Foamglas cellular glass insulation, was developed by Pittsburgh Corning and was later acquired by Owens Corning. It is made of cullet, foaming agent, modified additive and foaming accelerator. After fine pulverization and uniform mixing, it is melted at high temperature, foamed and annealed. An inorganic non-metallic glass material, it consists of a large number of uniform bubble structures with a diameter of 1 to 2 mm. Sound-absorbing Foamglas insulation is more than 50% open cell bubbles, and heat-insulating Foamglas is more than 75% closed-cell air bubbles, which can be adjusted according to the requirements of use through changes in production technical parameters.^[8] Similar products by other manufacturers are sold as 'cellular glass' or 'foam glass'.

Properties

Because this material is moisture-proof, fireproof, and anti-corrosive, and the glass material has the advantages of long-term use performance, it is favored for uses in harsh environments such as in heat insulation, deep cooling, underground, open-air, flammable, damp, and under chemical attack. It is widely used in wall insulation, petroleum, chemical industry, machine room noise reduction, highway sound absorption barrier, electric power, military products, etc. and is called green environmental protection insulation material by users.

Depending on the properties of the foam glass, it can be used as insulation material in various sectors of construction engineering, as well as in shipbuilding, chemical, cryogenic, and high-temperature technologies. White and stained glass are also used as sound absorbing and decorative materials. Waste in production – foamed glass powder and scrap can also be used as fillers for decorative light concrete and other applications. Depending on the application, foam glass products produced by the corresponding processes can be divided into four categories, namely insulating foam glass, sound-absorbing decorative foam glass, facing foam glass, and granular foam glass.

Foam glass is a kind of lightweight, high-strength building material and decorative material with excellent performance (insulation) and sound absorption that is both moisture-proof and fireproof. The temperature range is from -196 degrees to 450 degrees Celsius. Although other new insulation materials emerge in an endless stream, foam glass occupies an increasingly important position in the fields of low thermal insulation, moisture-proof engineering, and sound absorption due to its permanence, safety, and high reliability. Its production is the recycling of waste solid materials, which is an example of protecting the environment and obtaining substantial economic benefits. Recently, it is available in monolitic dimensions of 2.8 x 1.2m.

Lava foam glass: natural lava such as obsidian and industrial waste slag is used as the base material, and a certain amount of glass powder can also be added to reduce the foaming temperature and foam glass made of or the like as a foaming agent. Generally used as insulation materials and wall materials for construction and industrial equipment.^[9]

Application

Foam glass is fireproof, waterproof, non-toxic, corrosion-resistant, anti-mite, non-aging, non-radioactive, and insulating. Anti-magnetic wave, anti-static, high mechanical strength, with good adhesion to various types of mud. It is a stable building exterior wall and roof insulation, sound insulation, and waterproof material.

According to reports, foam glass can be used in places that require sound insulation and heat insulation, leak prevention and flood control. It has functions for home cleaning and health care. The use of foam glass to protect the heating duct reduces heat loss by approximately 25% compared to conventional protective materials.^[10]

Foam glass, also known as porous glass, is filled with numerous open or closed small pores. The area of the pores is 80%~90% of the total volume, and the pore size is 0.5~5mm, and some are as small as a few microns.

1. The matrix of the foam glass is glass, so it does not absorb water. The internal bubbles are also closed, so there is no capillary phenomenon and no penetration, so foam glass is currently the most ideal thermal insulation material. ^{[citation needed]}

2. The mechanical strength is high, and the intensity change is proportional to the apparent density. It has excellent pressure resistance and can withstand the erosion and load of the external environment more than other materials. The combination of excellent compression resistance and moisture barrier properties makes foam glass an ideal thermal insulation material for underground pipelines and tank foundations. ^{[citation needed]}

3. Foam glass has good thermal and moisture permeability, so thermal conductivity is stable for a long time, and it does not change due to environmental influences, and the thermal insulation performance is good.

4. Foam glass is a matrix wet glass, so it will not burn spontaneously and will not be burned. It is an excellent fireproof material. Foam glass has an operating temperature range of -200 to 430 °C, a small expansion coefficient (8 × 10 °C) and is reversible, so the material properties are unchanged for a long time, are not easy to embrittle, and have good stability.

5. Foam glass has good sound insulation performance and strong absorption of sound waves. The average penetration loss is 28.3 dB in 60~400 Hz.

6. The dyeing property of foam glass is good, so it can be used as insulation decoration materials.

Foam glass insulation aggregate is used in the same way as coated clay aggregate but is capable of being used as a load-bearing hardcore. It also offers better insulation (lambda/k value = 0.08 – approximately 20% lower thermal conductivity than lightweight expanded clay aggregate). It therefore needs less depth for similar thermal performance.^[11]

See also

• Nanofoam
• Metal foam
• Ceramic foam
• Porous medium
• Reticulated foam
• Foam glass gravel

References

1. Llaudis, Alejandro Saburit; Tari, María José Orts; Ten, Francisco Javier García; Bernardo, Enrico; Colombo, Paolo (July 2009). "Foaming of flat glass cullet using Si3N4 and MnO2 powders". Ceramics International. 35 (5): 1953–1959. doi:10.1016/j.ceramint.2008.10.022.
2. Bernardo, E.; Cedro, R.; Florean, M.; Hreglich, S. (August 2007). "Reutilization and stabilization of wastes by the production of glass foams". Ceramics International. 33 (6): 963–968. doi:10.1016/j.ceramint.2006.02.010.
3. Lv, Dong Sheng; Li, Xiu Hua; Wang, Lei; Du, Juan Juan; Zhang, Jie (April 2010). "Effect of Carbon as Foaming Agent on Pore Structure of Foam Glass". Advanced Materials Research. 105–106: 765–768. doi:10.4028/www.scientific.net/AMR.105-106.765. ISSN 1662-8985. S2CID 135917745.
4. Abdollahi, Sorosh; Yekta, Bijan Eftekhari (November 2020). "Prediction of foaming temperature of glass in the presence of various oxidizers via thermodynamics route". Ceramics International. 46 (16): 25626–25632. doi:10.1016/j.ceramint.2020.07.037. S2CID 225624462.
5. FR 752636 
6. Kitaygorodskiy, I.I. (1932). Transactions of the All-Union Conference on Standardization and Production of New Construction Materials. Moscow.{{cite book}}: CS1 maint: location missing publisher (link)
7. Kitaygorodskiy, I.I (1940). Proizvodstvo Stroitel'nikh Materialov. No 3. {{cite journal}}: |volume= has extra text (help); Missing or empty |title= (help)
8. "TRADE OF Industrial Insulation" (PDF). local.ecollege.ie. Retrieved 2018-12-12.
9. Swan, Robert H.; Yeom, Seungcheol; Sjoblom, Kurt J.; Stark, Timothy D.; Filshill, Archie (2016-08-08). Engineering Properties of Foamed Recycled Glass as a Lightweight Fill. Reston, VA: American Society of Civil Engineers. doi:10.1061/9780784480151.002. ISBN 9780784480151. {{cite book}}: |journal= ignored (help)
10. Jakob., Koenig. Fabrication of highly insulating foam glass made from CRT panel glass. OCLC 922865725.
11. "Foam Glass Insulation Aggregate: GEOCELL®". Mike Wye. Retrieved 2016-11-01.

 

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External links

• Yin, Hairong; Ma, Mingxin; Bai, Jianguang; Li, Yanxiao; Zhang, Sen; Wang, Fei (December 2016). "Fabrication of foam glass from iron tailings". Materials Letters. 185: 511–513. doi:10.1016/j.matlet.2016.09.034.
• Wang, Hao; Chen, Ziwei; Ji, Ru; Liu, Lili; Wang, Xidong (August 2018). "Integrated utilization of high alumina fly ash for synthesis of foam glass ceramic". Ceramics International. 44 (12): 13681–13688. doi:10.1016/j.ceramint.2018.04.207. S2CID 139498288.
• Foam glass -Britannica online
• GE Wei-qing; YANG Jing (2008). "The Study of the Present Situation of Foam Glass and Development Trend in China". Journal of Tangshan College. 21 (2): 66–67, 86. ISSN 1672-349X.