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Wikipedia

Dimethyl-4-phenylenediamine

Dimethyl-4-phenylenediamine is an amine. It has been used as an accelerator for the vulcanization of rubber.[2] It can be used in oxidase tests.

Dimethyl-4-phenylenediamine
Names
Preferred IUPAC name
N1,N1-Dimethylbenzene-1,4-diamine
Other names
p-Aminodimethylaniline; N,N-Dimethyl-p-phenylenediamine; 4-(Dimethylamino)aniline; p-Amino-N,N-dimethylaniline; p-(Dimethylamino)aniline; DMPPDA; Dimethyl-p-phenylenediamine; 4-Amino-N,N-dimethylaniline; p-Dimethylaminophenylamine; DMPD
Identifiers
  • 99-98-9 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 13884246 Y
ECHA InfoCard 100.002.552
  • 7472
UNII
  • 7GZH2FMK7X N
  • DTXSID6025149
  • CN(C)C1=CC=C(C=C1)N
Properties
C8H12N2
Molar mass 136.198 g·mol−1
Appearance Reddish-violet crystals[1]
Melting point 53 °C (127 °F; 326 K)[1]
Boiling point 262 °C (504 °F; 535 K)[1]
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

Synthesis edit

Dimethyl-4-phenylenediamine is made by the nitrosylation of dimethylaniline followed by reduction.

Applications edit

Dimethyl-4-phenylenediamine can be converted to methylene blue by reaction with dimethylaniline and sodium thiosulfate in several steps:[3]

 

It is used as accelerator for the vulcanization of rubber, being first converted to the corresponding mercaptobenzothiazole.

 

References edit

  1. ^ a b c Merck Index, 11th Edition, 3242
  2. ^ Geer, W. C.; Bedford, C. W. (January 24, 1925). "The History of Organic Accelerators in the Rubber Industry". Industrial and Engineering Chemistry. 17 (4): 393–396. doi:10.1021/ie50184a021.
  3. ^ Horst Berneth (2012). "Azine Dyes". Ullmann's Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a03_213.pub3. ISBN 9783527303854.

dimethyl, phenylenediamine, amine, been, used, accelerator, vulcanization, rubber, used, oxidase, tests, names, preferred, iupac, name, dimethylbenzene, diamine, other, names, aminodimethylaniline, dimethyl, phenylenediamine, dimethylamino, aniline, amino, dim. Dimethyl 4 phenylenediamine is an amine It has been used as an accelerator for the vulcanization of rubber 2 It can be used in oxidase tests Dimethyl 4 phenylenediamine Names Preferred IUPAC name N1 N1 Dimethylbenzene 1 4 diamine Other names p Aminodimethylaniline N N Dimethyl p phenylenediamine 4 Dimethylamino aniline p Amino N N dimethylaniline p Dimethylamino aniline DMPPDA Dimethyl p phenylenediamine 4 Amino N N dimethylaniline p Dimethylaminophenylamine DMPD Identifiers CAS Number 99 98 9 Y 3D model JSmol Interactive image ChemSpider 13884246 Y ECHA InfoCard 100 002 552 PubChem CID 7472 UNII 7GZH2FMK7X N CompTox Dashboard EPA DTXSID6025149 SMILES CN C C1 CC C C C1 N Properties Chemical formula C 8H 12N 2 Molar mass 136 198 g mol 1 Appearance Reddish violet crystals 1 Melting point 53 C 127 F 326 K 1 Boiling point 262 C 504 F 535 K 1 Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox referencesSynthesis editDimethyl 4 phenylenediamine is made by the nitrosylation of dimethylaniline followed by reduction Applications editDimethyl 4 phenylenediamine can be converted to methylene blue by reaction with dimethylaniline and sodium thiosulfate in several steps 3 nbsp It is used as accelerator for the vulcanization of rubber being first converted to the corresponding mercaptobenzothiazole nbsp References edit a b c Merck Index 11th Edition 3242 Geer W C Bedford C W January 24 1925 The History of Organic Accelerators in the Rubber Industry Industrial and Engineering Chemistry 17 4 393 396 doi 10 1021 ie50184a021 Horst Berneth 2012 Azine Dyes Ullmann s Encyclopedia of Industrial Chemistry Weinheim Wiley VCH doi 10 1002 14356007 a03 213 pub3 ISBN 9783527303854 Retrieved from https en wikipedia org w index php title Dimethyl 4 phenylenediamine amp oldid 1193316593, wikipedia, wiki, book, books, library,

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