Button cell
A button cell, watch battery, or coin battery is a small single-cell battery shaped as a squat cylinder typically 5 to 25 mm (0.197 to 0.984 in) in diameter and 1 to 6 mm (0.039 to 0.236 in) high — resembling a button. Stainless steel usually forms the bottom body and positive terminal of the cell; insulated from it, the metallic top cap forms the negative terminal.
Button cells are used to power small portable electronics devices such as wrist watches and pocket calculators. Wider variants are usually called coin cells. Devices using button cells are usually designed around a cell giving a long service life, typically well over a year in continuous use in a wristwatch. Most button cells have low self-discharge, holding their charge for a long time if not used. Relatively high-power devices such as hearing aids may use a zinc–air battery, which has a much higher capacity for a given size, but dries out after a few weeks even if not used.
Button cells are single cells, usually disposable primary cells. Common anode materials are zinc or lithium. Common cathode materials are manganese dioxide, silver oxide, carbon monofluoride, cupric oxide or oxygen from the air. Mercuric oxide button cells were formerly common, but are no longer available due to the toxicity and environmental effects of mercury.
Button cells are dangerous for small children, as when swallowed they can cause severe internal burns and significant injury or death.[1] Duracell has attempted to mitigate this by adding a bitter coating to their batteries.[2]
Properties of cell chemistries
Cells of different chemical composition made in the same size are mechanically interchangeable. However, the composition can affect service life and voltage stability. Using the wrong cell may lead to short life or improper operation (for example, light metering on a camera requires a stable voltage, thus silver cells are usually specified). Sometimes different cells of the same type, size and capacity are optimized for different loads by using different electrolytes, so that one may have longer service life than the other when supplying a relatively high current.
Alkaline batteries are made in the same button sizes as the other types, but typically provide less capacity and less stable voltage than more costly silver oxide or lithium cells.[3]
Silver cells may have an output voltage that is stable until it suddenly drops at end of life. This varies for individual types; one manufacturer (Energizer) offers three silver oxide cells of the same size, 357–303, 357-303H and EPX76, with capacities ranging from 150 to 200 mAh, voltage characteristics ranging from gradually reducing to fairly constant, and some stated to be for continuous low drain with high pulse on demand, others for photo use.[citation needed]
Mercury batteries also supply a stable voltage, but are now banned in many countries due to their toxicity and environmental impact.
Zinc-air batteries use air as the depolarizer and have much higher capacity than other types, as they take that air from the atmosphere. Cells have an air-tight seal which must be removed before use; they will then dry out in a few weeks, regardless of use.
For comparison, the properties of some cells from one manufacturer with diameter 11.6 mm and height 5.4 mm were listed in 2009 as:[4]
- Silver: capacity 200 mAh to an end-point of 0.9 V, internal resistance 5–15 Ω, weight 2.3 g
- Alkaline (manganese dioxide): 150 mAh (0.9), 3–9 Ω, 2.4 g
- Mercury: 200 mAh, 2.6 g
- Zinc-air: 620 mAh, 1.9 g
Examining datasheets for a manufacturer's range[4] may show a high-capacity alkaline cell with a capacity as high as one of the lower-capacity silver types; or a particular silver cell with twice the capacity of a particular alkaline cell. If the powered equipment requires a relatively high voltage (e.g., 1.3 V) to operate correctly, a silver cell with a flat discharge characteristic will give much longer service than an alkaline cell—even if it has the same specified capacity in mAh to an end-point of 0.9 V. If a device seems to "eat up" batteries after the original supplied by the manufacturer is replaced, it may be useful to check the device's requirements and the replacement battery's characteristics. For digital calipers, in particular, some are specified to require at least 1.25 V to operate and others 1.38 V.[5][6]
While alkaline, silver oxide, and mercury batteries of the same size may be mechanically interchangeable in any given device, use of a cell of the right voltage but unsuitable characteristics can lead to short battery life or failure to operate equipment. Common lithium primary cells, with a terminal voltage around 3 volts, are not made in sizes interchangeable with 1.5 volt cells. Use of a battery of significantly higher voltage than equipment is designed for can cause permanent damage.
Type designation
International standard IEC 60086-3 defines an alphanumeric coding system for "Watch batteries". Manufacturers often have their own naming system; for example, the cell called LR1154 by the IEC standard is named AG13, LR44, 357, A76, and other names by different manufacturers. The IEC standard and some others encode the case size so that the numeric part of the code is uniquely determined by the case size; other codes do not encode size directly.
Examples of batteries conforming to the IEC standard are CR2032, SR516, and LR1154, where the letters and numbers indicate the following characteristics.
Electrochemical system
The first letter in the IEC standard system identifies the chemical composition of the battery, which also implies a nominal voltage:
| Letter code | Common name | Positive electrode | Electrolyte | Negative electrode | Nominal voltage (V) | End-point voltage (V) |
|---|---|---|---|---|---|---|
| L | Alkaline | Manganese dioxide | Alkali | Zinc | 1.5 | 1.0 |
| S | Silver | Silver oxide | Alkali | Zinc | 1.55 | 1.2 |
| P | Zinc-air | Oxygen | Alkali | Zinc | 1.4 | 1.2 |
| C | Lithium | Manganese dioxide | Organic | Lithium | 3 | 2.0 |
| B | Carbon monofluoride | Organic | Lithium | 3 | 2.0 | |
| G | Copper oxide | Organic | Lithium | 1.5 | 1.2 | |
| Z | Nickel oxyhydroxide | Manganese dioxide, nickel oxyhydroxide | Alkali | Zinc | 1.5 | ? |
| M, N (withdrawn) | Mercury | Mercuric oxide | Alkali | Zinc | 1.35/1.40 | 1.1 |
For types with stable voltage falling precipitously at end-of-life (cliff-top voltage-versus-time graph), the end-voltage is the value at the "cliff-edge", after which the voltage drops extremely rapidly. For types which lose voltage gradually (slope graph, no cliff-edge), the end-point is the voltage beyond which further discharge will cause damage to either the battery or the device it is powering, typically 1.0 or 0.9 V.
Common names are conventional rather than uniquely descriptive; for example, a silver (oxide) cell has an alkaline electrolyte.
L, S, and C type cells are today the most commonly used types in quartz watches, calculators, small PDA devices, computer clocks, and blinky lights. Miniature zinc-air batteries – P type – are used in hearing aids and medical instruments. In the IEC system, larger cells may have no prefix for the chemical system, indicating they are zinc-carbon batteries; such types are not available in button cell format.
The second letter, R, indicates a round (cylindrical) form.
The standard only describes primary batteries. Rechargeable types made in the same case size will carry a different prefix not given in the IEC standard, for example some ML and LiR button cells use rechargeable lithium technology.
Package size
Package size of button batteries using standard names is indicated by a 2-digit code representing a standard case size, or a 3- or 4-digit code representing the cell diameter and height. The first one or two digits encode the outer diameter of the battery in whole millimeters, rounded down; exact diameters are specified by the standard, and there is no ambiguity; e.g., any cell with an initial 9 is 9.5 mm in diameter, no other value between 9.0 and 9.9 is used. The last two digits are the overall height in tenths of a millimeter.
| Number code | Nominal diameter (mm) | Tolerance (mm) |
|---|---|---|
| 4 | 4.8 | ±0.15 |
| 5 | 5.8 | ±0.15 |
| 6 | 6.8 | ±0.15 |
| 7 | 7.9 | ±0.15 |
| 9 | 9.5 | ±0.15 |
| 10 | 10.0 | ±0.20 |
| 11 | 11.6 | ±0.20 |
| 12 | 12.5 | ±0.25 |
| 16 | 16.0 | ±0.25 |
| 20 | 20.0 | ±0.25 |
| 23 | 23.0 | ±0.50 |
| 24 | 24.5 | ±0.50 |
| 44 | 11.6 | ±0.20 |
Examples:
- CR2032: lithium, 20 mm diameter, 3.2 mm height, 220 mAh
- CR2032H; lithium, 20 mm diameter, 3.2 mm height 240 mAh
- CR2025: lithium, 20 mm diameter, 2.5 mm height, 170 mAh
- SR516: silver, 5.8 mm diameter, 1.6 mm height
- LR1154/SR1154: alkaline/silver, 11.6 mm diameter, 5.4 mm height. The two-digit codes LR44/SR44 are often used for this size
Some coin cells, particularly lithium, are made with solder tabs for permanent installation, such as to power memory for configuration information of a device. The complete nomenclature will have prefixes and suffixes to indicate special terminal arrangements. For example, there is a plug-in and a solder-in CR2032, a plug-in and three solder-in BR2330s in addition to CR2330s, and many rechargeables in 2032, 2330, and other sizes.[7]
Letter suffix
After the package code, the following additional letters may optionally appear in the type designation to indicate the electrolyte used:
- P: potassium hydroxide electrolyte
- S: sodium hydroxide electrolyte
- No letter: organic electrolyte
- SW: low drain type for quartz watches (analog or digital) without light, alarm, or chronograph functions
- W: high drain type for all quartz watches, calculators and cameras. The battery complies with all the requirements of the international IEC 60086-3[8] standard for watch batteries.
Other package markings
Apart from the type code described in the preceding section, watch batteries should also be marked with
- the name or trademark of the manufacturer or supplier;
- the polarity (+);
- the date of manufacturing.
Date codes
Often a 2-letter code (sometimes on the side of the battery) where the first letter identifies the manufacturer and the second is the year of manufacture. For example:
- YN – the letter N is the 14th letter in the alphabet – indicates the cell was manufactured in 2014.
There is no universal standard.
The manufacturing date can be abbreviated to the last digit of the year, followed by a digit or letter indicating the month, where O, Y, and Z are used for October, November and December, respectively (e.g., 01 = January 2010 or 2000, 9Y = November 2019 or 2009).
Common manufacturer code
A code used by some manufacturers is AG (alkaline) or SG (silver) followed by a number, as follows
| G code | IEC code |
|---|---|
| xG0 | 521 |
| xG1 | 621 |
| xG2 | 726 |
| xG3 | 736 |
| xG4 | 626 |
| xG5 | 754 |
| xG6 | 920 or 921 |
| xG7 | 926 or 927 |
| xG8 | 1120 or 1121 |
| xG9 | 936 |
| xG10 | 1130 or 1131 |
| xG11 | 721 |
| xG12 | 1142 |
| xG13 | 1154 |
To those familiar with the chemical symbol for silver, Ag, this may suggest incorrectly that AG cells are silver.
Rechargeable variants
In addition to disposable (single use) button cells, rechargeable batteries in many of the same sizes are available, with lower capacity than disposable cells. Disposable and rechargeable batteries are manufactured to fit into a holder or with solder tags for permanent connection. In equipment with a battery holder, disposable or rechargeable batteries may be used, if the voltage is compatible.
A typical use for a small rechargeable battery (in coin or other format) is to back up the settings of equipment which is normally permanently mains-powered, in the case of power failure. For example, many central heating controllers store operation times and similar information in volatile memory, lost in the case of power failure. It is usual for such systems to include a backup battery, either a disposable in a holder (current drain is extremely low and life is long) or a soldered-in rechargeable.[9]
Rechargeable NiCd button cells were often components of the backup battery of older computers; non-rechargeable lithium button cells with a lifetime of several years are used in later equipment.
Rechargeable batteries typically have the same dimension-based numeric code with different letters; thus CR2032 is a disposable battery while ML2032, VL2032 and LIR2032 are rechargeables that fit in the same holder if not fitted with solder tags. It is mechanically possible, though hazardous, to fit a disposable battery in a holder intended for a rechargeable; holders are fitted in parts of equipment only accessible by service personnel in such cases.
Health issues
Accidental ingestion
Button cells are attractive to small children; they may put them in their mouth and swallow them. The ingested battery can cause significant damage to internal organs. The battery reacts with bodily fluids, such as mucus or saliva, creating a circuit which can release an alkali that is strong enough to burn through human tissue.[11][12]
Swallowed batteries can cause damage to the lining of the esophagus, and can create a hole in the esophagus lining in two hours.[11] In severe cases, damage can cause a passage between the esophagus and the trachea. Swallowed button cells can damage the vocal cords. They can even burn through the blood vessels in the chest area, including the aorta.[11] In the United States, 44 child deaths were reported from button battery ingestion in 2002–2021.[12]
In Greater Manchester, England, with a population of 2,700,000, two children between 12 months and six years old died, and five suffered life-changing injuries, in the 18 months leading up to October 2014. In the United States, on average, over 3,000 pediatric ingestions of button batteries are reported annually. The proportion of major and fatal outcomes is increasing.[13] Coin cells of diameter 20 mm or greater cause the most serious injuries, even if expended and intact.[13][14] In Auckland, New Zealand as of 2018 there are about 20 cases per year requiring hospitalization.[15]
In 2020, Duracell announced that they were coating some of their lithium button cells with a bitterant compound to discourage children from ingesting them.[16] An alternative solution is to design (or litigate) the offending cells, mostly 20mm lithium cells, out of the supply chain.[17]
Children most at risk of button battery ingestion are those aged 5 years and under.[17] Three child deaths in Australia reveal that in each case: i) the ingestion was not witnessed, ii) the source of the battery remains unknown, iii) initial misdiagnosis delayed appropriate intervention, iv) diagnosis was confirmed by X-ray, v) in each case the battery lodged in the child's oesophagus, vi) the offending batteries were 20mm lithium cells, vii) death occurred 19 days to 3 weeks after ingestion.[17] The presenting symptoms of button cell ingestion may be misdiagnosed and attributed to common non life-threatening childhood maladies.
Mercury and cadmium
Some button cells contain mercury or cadmium, which are toxic. In early 2013 the European Parliament Environment Committee voted for a ban on the export and import of a range of mercury-containing products such as button cells and other batteries, to be imposed from 2020.[18][19]
See also
References
- ^ "See what a button battery can do to a child's throat". BBC News Online. 22 September 2016. from the original on 22 September 2016.
- ^ "Duracell Is Making Coin Batteries Taste Horrible on Purpose". PCMAG. Retrieved 2022-02-17.
- ^ Alkaline button cell. amazon.co.uk. A card marked with the name Hyundai with 30 button cells in 5 sizes made in China, stating that they are alkaline but with pictures of watches, calculators, etc. is sold for prices ranging from about £1 to £4 in the UK
- ^ a b Energizer website 2009-08-28 at the Wayback Machine, with datasheets for many batteries of several chemistries
- ^ Buying Button Cells for Digital Calipers 2010-07-27 at the Wayback Machine. Truetex.com. Retrieved on 2015-11-08.
- ^ Caliper Battery Life 2010-06-21 at the Wayback Machine. Davehylands.com. Retrieved on 2015-11-08.
- ^ Panasonic CR battery data page 2013-07-02 at the Wayback Machine, showing many batteries in plug-in and horizontal and vertical solder versions. The same site lists rechargeable cells with various chemistries, in the same sizes and options as disposable batteries of the same size code and hence mechanically interchangeable, though carrying risks of malfunctioning and damage.
- ^ IEC 60086-3 Standard for Watch Batteries (withdrawn) 2013-06-27 at the Wayback Machine. (PDF) . Just scope/preview. Retrieved on 2015-11-08.
- ^ Datasheet of a mains-powered smoke alarm, with models backed up by disposable battery or by rechargeable UL2330 button battery 2013-08-05 at the Wayback Machine. Kiddefirex.co.uk (2015-10-01). Retrieved on 2015-11-08.
- ^ "Clause 9: Marking and packaging". IEC 60086-4:2019 Primary batteries - Part 4: Safety of lithium batteries (PDF). Geneva: IEC. ISBN 978-2-8322-6808-7.
- ^ a b c "Button batteries – using them safely". Great Ormond Street Hospital. Great Ormond Street Hospital for Children. October 2018. Retrieved 2019-10-19.
- ^ a b Paull, John (2022) Silent Nursery: Button Battery Fatalities in Children – the Long Road from Externality to Obsolescence, International Journal of Clinical and Experimental Medicine Research, 6 (3): 301–308.
- ^ a b "Button Battery Statistics". www.poison.org. Retrieved 2018-06-30.
- ^ Litovitz, Toby; Whitaker, Nicole; Clark, Lynn; White, Nicole C.; Marsolek, Melinda (2010-06-01). "Emerging Battery-Ingestion Hazard: Clinical Implications". Pediatrics. 125 (6): 1168–1177. doi:10.1542/peds.2009-3037. ISSN 0031-4005. PMID 20498173.
- ^ "Risk of swallowing deadly button batteries prompts new industry safety policy". Stuff. February 2018. Retrieved 2018-04-07.
- ^ Gartenberg, Chaim (2020-09-29). "Duracell's new coin batteries have a bitter coating that makes them taste terrible". The Verge. Retrieved 2020-09-29.
- ^ a b c Paull, John (2021). Button batteries and child deaths: Market failure of unsafe products, International Journal of Clinical and Experimental Medicine Research, 2021, 5(3), 297–303
- ^ "EUBatteryDirective (2006/66/EC) Summary" (PDF). 8 December 2009. Eveready Battery Company, Inc. (PDF) from the original on 10 July 2012. Retrieved 20 June 2013.148 Kb
- ^ "Directive 2013/56/EU amending Directive 2006/66/EC" 2016-03-04 at the Wayback Machine, European Parliament & Council, 20 November 2013, Retrieved 7 April 2015
Sources
- IEC 60086-3: Primary batteries – Part 3: Watch batteries. International Electrotechnical Commission, Geneva, 1995. (also: BS EN 60086-3:1996)
- Sample of data sheets available from Energizer : "CR2032 Technical Details" (PDF). (56.2 KiB)
- "An Investigation of Alternatives to Miniature Batteries Containing Mercury" (PDF). (440 KiB)
External links
- Coin cell reference table
- Watch battery cross reference table
- (PDF). Archived from the original (PDF) on 2013-11-02. (includes discharge characteristics)
- "DIRECTIVE 2006/66/EC OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL". (407 Kb) 6 September 2006 (re recycling and disposal of batteries)