Both the mono- and bis(triphenylphosphine) complexes were originally described by Walter Reppe.[5]
Referencesedit
^Clifford, A. F.; Mukherjee, A. K. (1966). "Iron Carbonyl Complexes of Triphenylphosphine, Triphenylarsine, and Triphenylstibine". Inorganic Syntheses. Vol. VIII. pp. 185–191. doi:10.1002/9780470132395.ch49. ISBN9780470131671.
^Therien, M. J.; Trogler, W. C. (1990). "Bis(Phosphine) Derivatives of Iron Pentacarbonyl and Tetracarbonyl (Tri- tert -Butylphosphine)Iron(O)". Inorganic Syntheses. Vol. 28. pp. 173–9. doi:10.1002/9780470132593.ch45. ISBN9780471526193. {{cite book}}: |journal= ignored (help)
^Keiter, Richard L.; Keiter, Ellen A.; Boecker, Carol A.; Miller, David R.; Hecker, Karl H. (1997). "Tricarbonylbis(Phosphine)Iron(0) Complexes". Inorganic Syntheses. Vol. 31. pp. 210–214. doi:10.1002/9780470132623.ch31. ISBN9780470132623.
^Sowa, John R.; Zanotti, Valerio; Facchin, Giacomo; Angelici, Robert J. (1991). "Heats of Protonation of Transition-Metal Complexes: The Effect of Phosphine Basicity on Metal Basicity in CpIr(CO)(PR3) and Fe(CO)3(PR3)2". Journal of the American Chemical Society. 113 (24): 9185–9192. doi:10.1021/ja00024a026.
^Reppe, Walter; Schweckendiek, Walter Joachim (1948). "Cyclisierende Polymerisation von Acetylen. III Benzol, Benzolderivate und hydroaromatische Verbindungen". Justus Liebigs Annalen der Chemie. 560: 104–116. doi:10.1002/jlac.19485600104.
January 01, 1970
triphenylphosphine, iron, tricarbonyl, tricarbonylbis, triphenylphosphine, iron, coordination, complex, with, formula, pph3, c6h5, yellow, solid, this, complex, derived, from, iron, pentacarbonyl, replacement, carbonyl, ligands, triphenylphosphine, pph3, ident. Tricarbonylbis triphenylphosphine iron 0 is a coordination complex with the formula Fe CO 3 PPh3 2 Ph C6H5 A yellow solid this complex is derived from iron pentacarbonyl by replacement of two carbonyl ligands by triphenylphosphine PPh3 Bis triphenylphosphine iron tricarbonyl Identifiers CAS Number 21255 52 7 3D model JSmol Interactive image ChemSpider 4807608 PubChem CID 6097100 InChI InChI 1S 2C18H15P 3CO Fe c2 1 4 10 16 11 5 1 19 17 12 6 2 7 13 17 18 14 8 3 9 15 18 3 1 2 h2 1 15H Key NPCXYZUUVGQEGS UHFFFAOYSA N SMILES C O C O C O C1 CC C C C1 P C2 CC CC C2 C3 CC CC C3 C1 CC C C C1 P C2 CC CC C2 C3 CC CC C3 Fe Properties Chemical formula C 39H 30Fe O 3P 2 Molar mass 664 459 g mol 1 Appearance yellow solid Melting point 262 266 C 504 511 F 535 539 K decomp Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa Infobox referencesStrynthesis and reactions editThe title complex can be prepared by reaction of triiron dodecacarbonyl with excess triphenylphosphine 1 Fe3 CO 12 6 P C6H5 3 3 Fe CO 3 P C6H5 3 2 3 CO Triphenylphosphine iron tetracarbonyl is an intermediate in the synthesis of this compound The title complex can also be produced more efficiently by borohydride catalyzed substitution of iron pentacarbonyl 2 3 Protonation gives the ferrous hydride 4 Fe CO 3 P C6H5 3 2 HBF4 HFe CO 3 P C6H5 3 2 BF4 Both the mono and bis triphenylphosphine complexes were originally described by Walter Reppe 5 References edit Clifford A F Mukherjee A K 1966 Iron Carbonyl Complexes of Triphenylphosphine Triphenylarsine and Triphenylstibine Inorganic Syntheses Vol VIII pp 185 191 doi 10 1002 9780470132395 ch49 ISBN 9780470131671 Therien M J Trogler W C 1990 Bis Phosphine Derivatives of Iron Pentacarbonyl and Tetracarbonyl Tri tert Butylphosphine Iron O Inorganic Syntheses Vol 28 pp 173 9 doi 10 1002 9780470132593 ch45 ISBN 9780471526193 a href Template Cite book html title Template Cite book cite book a journal ignored help Keiter Richard L Keiter Ellen A Boecker Carol A Miller David R Hecker Karl H 1997 Tricarbonylbis Phosphine Iron 0 Complexes Inorganic Syntheses Vol 31 pp 210 214 doi 10 1002 9780470132623 ch31 ISBN 9780470132623 Sowa John R Zanotti Valerio Facchin Giacomo Angelici Robert J 1991 Heats of Protonation of Transition Metal Complexes The Effect of Phosphine Basicity on Metal Basicity in CpIr CO PR3 and Fe CO 3 PR3 2 Journal of the American Chemical Society 113 24 9185 9192 doi 10 1021 ja00024a026 Reppe Walter Schweckendiek Walter Joachim 1948 Cyclisierende Polymerisation von Acetylen III Benzol Benzolderivate und hydroaromatische Verbindungen Justus Liebigs Annalen der Chemie 560 104 116 doi 10 1002 jlac 19485600104 Retrieved from https en wikipedia org w index php title Bis triphenylphosphine iron tricarbonyl amp oldid 1209118340, wikipedia, wiki, book, books, library,
