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Butyl PBD

Butyl PBD or b-PBD (short for butyl-phenyl-bipheny-oxydiazole[1]) is a fluorescent organic compound used in the Liquid Scintillator Neutrino Detector (LSND) at Los Alamos National Laboratory, USA.[1]

Butyl PBD
Names
Preferred IUPAC name
2-([1,1′-Biphenyl]-4-yl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole
Other names
2-(4-tert-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole
2-(4-Biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole
Identifiers
  • 15082-28-7 Y
3D model (JSmol)
  • Interactive image
ChemSpider
  • 76483 Y
ECHA InfoCard 100.035.563
EC Number
  • 239-135-7
  • 84782
UNII
  • YKR9AP6LRZ Y
  • DTXSID5065851
  • InChI=1S/C24H22N2O/c1-24(2,3)21-15-13-20(14-16-21)23-26-25-22(27-23)19-11-9-18(10-12-19)17-7-5-4-6-8-17/h4-16H,1-3H3 Y
    Key: XZCJVWCMJYNSQO-UHFFFAOYSA-N Y
  • InChI=1/C24H22N2O/c1-24(2,3)21-15-13-20(14-16-21)23-26-25-22(27-23)19-11-9-18(10-12-19)17-7-5-4-6-8-17/h4-16H,1-3H3
    Key: XZCJVWCMJYNSQO-UHFFFAOYAT
  • CC(C)(C)c1ccc(cc1)c2nnc(o2)c3ccc(cc3)c4ccccc4
Properties
C24H22N2O
Molar mass 354.44 g mol−1
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
N verify (what is YN ?)

The fluorescent emission of b-PBD is at λem = 364 nm for excitation at λex = 305 nm (in ethanol solution).[2] As a scintillant in the LSND, it was used at a concentration of 31 mg/L (87 μmol/L) dissolved in mineral oil.[1]

References edit

  1. ^ a b c Athanassopoulos, C.; Auerbach, L. B.; Bauer, D.; Bolton, R. D.; Burman, R. L.; Cohen, I.; Caldwell, D. O.; Dieterle, B. D.; Donahue, J. B.; Eisner, A. M.; Fazely, A.; Federspiel, F. J.; M. Gray, G. T. Garvey; Gunasingha, R. M.; Highland, V.; Imlay, R.; Johnston, K.; Kim, H. J.; Louis, W. C.; Lu, A.; Margulies, J.; Mills, G. B.; McIlhany, K.; Metcalf, W.; Reeder, R. A.; Sandberg, V.; Schillaci, M.; Smith, D.; Stancu, I.; Strossman, W.; Tayloe, R.; Van Dalen, G. J.; Vernon, W.; Wang, Y-X.; White, D. H.; Whitehouse, D.; Works, D.; Xiao, Y.; Yellin, S. (1997), "The Liquid Scintillator Neutrino Detector and LAMPF Neutrino Source", Nucl. Instrum. Methods A, 388: 149–72, arXiv:nucl-ex/9605002v1, Bibcode:1997NIMPA.388..149A, doi:10.1016/S0168-9002(96)01155-2.
  2. ^ B8378 2-(4-tert-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole ≥99%, Sigma-Aldrich, retrieved 2010-05-22.

butyl, short, butyl, phenyl, bipheny, oxydiazole, fluorescent, organic, compound, used, liquid, scintillator, neutrino, detector, lsnd, alamos, national, laboratory, names, preferred, iupac, name, biphenyl, tert, butylphenyl, oxadiazole, other, names, tert, bu. Butyl PBD or b PBD short for butyl phenyl bipheny oxydiazole 1 is a fluorescent organic compound used in the Liquid Scintillator Neutrino Detector LSND at Los Alamos National Laboratory USA 1 Butyl PBD Names Preferred IUPAC name 2 1 1 Biphenyl 4 yl 5 4 tert butylphenyl 1 3 4 oxadiazole Other names 2 4 tert Butylphenyl 5 4 biphenylyl 1 3 4 oxadiazole2 4 Biphenylyl 5 4 tert butylphenyl 1 3 4 oxadiazole Identifiers CAS Number 15082 28 7 Y 3D model JSmol Interactive image ChemSpider 76483 Y ECHA InfoCard 100 035 563 EC Number 239 135 7 PubChem CID 84782 UNII YKR9AP6LRZ Y CompTox Dashboard EPA DTXSID5065851 InChI InChI 1S C24H22N2O c1 24 2 3 21 15 13 20 14 16 21 23 26 25 22 27 23 19 11 9 18 10 12 19 17 7 5 4 6 8 17 h4 16H 1 3H3 YKey XZCJVWCMJYNSQO UHFFFAOYSA N YInChI 1 C24H22N2O c1 24 2 3 21 15 13 20 14 16 21 23 26 25 22 27 23 19 11 9 18 10 12 19 17 7 5 4 6 8 17 h4 16H 1 3H3Key XZCJVWCMJYNSQO UHFFFAOYAT SMILES CC C C c1ccc cc1 c2nnc o2 c3ccc cc3 c4ccccc4 Properties Chemical formula C24H22N2O Molar mass 354 44 g mol 1 Except where otherwise noted data are given for materials in their standard state at 25 C 77 F 100 kPa N verify what is Y N Infobox references The fluorescent emission of b PBD is at lem 364 nm for excitation at lex 305 nm in ethanol solution 2 As a scintillant in the LSND it was used at a concentration of 31 mg L 87 mmol L dissolved in mineral oil 1 References edit a b c Athanassopoulos C Auerbach L B Bauer D Bolton R D Burman R L Cohen I Caldwell D O Dieterle B D Donahue J B Eisner A M Fazely A Federspiel F J M Gray G T Garvey Gunasingha R M Highland V Imlay R Johnston K Kim H J Louis W C Lu A Margulies J Mills G B McIlhany K Metcalf W Reeder R A Sandberg V Schillaci M Smith D Stancu I Strossman W Tayloe R Van Dalen G J Vernon W Wang Y X White D H Whitehouse D Works D Xiao Y Yellin S 1997 The Liquid Scintillator Neutrino Detector and LAMPF Neutrino Source Nucl Instrum Methods A 388 149 72 arXiv nucl ex 9605002v1 Bibcode 1997NIMPA 388 149A doi 10 1016 S0168 9002 96 01155 2 B8378 2 4 tert Butylphenyl 5 4 biphenylyl 1 3 4 oxadiazole 99 Sigma Aldrich retrieved 2010 05 22 Retrieved from https en wikipedia org w index php title Butyl PBD amp oldid 1151890932, wikipedia, wiki, book, books, library,

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