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Wikipedia

Phosphoryl chloride (data page)

October 19, 2023

This page provides supplementary chemical data on phosphoryl chloride.

Material Safety Data Sheets Edit

  • Aldrich MSDS
  • Fisher MSDS
  • Baker MSDS

Thermodynamic properties Edit

Phase behavior
Triple point ? K (? °C), ? Pa
Critical point 602 K (329 °C), ? Pa
Std enthalpy change
of fusion, ΔfusHo		 ? kJ/mol
Std entropy change
of fusion, ΔfusSo		 ? J/(mol·K)
Std enthalpy change
of vaporization, ΔvapHo		 +33. kJ/mol
Std entropy change
of vaporization, ΔvapSo		 ? J/(mol·K)
Solid properties
Std enthalpy change
of formation, ΔfHosolid		 −610.0 kJ/mol
Standard molar entropy,
Sosolid		 ? J/(mol K)
Heat capacity, cp ? J/(mol K)
Liquid properties
Std enthalpy change
of formation, ΔfHoliquid		 −597.0 kJ/mol
Standard molar entropy,
Soliquid		 ? J/(mol K)
Heat capacity, cp ? J/(mol K)
Gas properties
Std enthalpy change
of formation, ΔfHogas		 −592.0 kJ/mol
Std Gibbs' free energy
change of formation, ΔfGogas		 −545.2 kJ/mol
Standard molar entropy,
Sogas		 325 J/(mol K)
Heat capacity, cp ? J/(mol K)

Spectral data Edit

UV-Vis
Lambda-max ? nm
Extinction coefficient ?
IR
Major absorption bands ? cm−1
NMR
Phosphorus-31 NMR 2.2 ppm upfield of H3PO4
MS
Masses of
main fragments

Structure and properties data Edit

Structure and properties
Index of refraction 1.460
Dielectric constant 13 C2/(N·m2) at 22 °C
Bond strength 533.5 kJ/mol (P=O)
Bond length 158 pm (P=O)
202 pm (P-Cl)
Bond angle 103° (Cl-P-Cl)
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References Edit

October 19, 2023
phosphoryl, chloride, data, page, this, page, provides, supplementary, chemical, data, phosphoryl, chloride, contents, material, safety, data, sheets, thermodynamic, properties, spectral, data, structure, properties, data, referencesmaterial, safety, data, she. This page provides supplementary chemical data on phosphoryl chloride Contents 1 Material Safety Data Sheets 2 Thermodynamic properties 3 Spectral data 4 Structure and properties data 5 ReferencesMaterial Safety Data Sheets EditAldrich MSDS Fisher MSDS Baker MSDSThermodynamic properties EditPhase behaviorTriple point K C PaCritical point 602 K 329 C PaStd enthalpy changeof fusion DfusHo kJ molStd entropy changeof fusion DfusSo J mol K Std enthalpy changeof vaporization DvapHo 33 kJ molStd entropy changeof vaporization DvapSo J mol K Solid propertiesStd enthalpy changeof formation DfHosolid 610 0 kJ molStandard molar entropy Sosolid J mol K Heat capacity cp J mol K Liquid propertiesStd enthalpy changeof formation DfHoliquid 597 0 kJ molStandard molar entropy Soliquid J mol K Heat capacity cp J mol K Gas propertiesStd enthalpy changeof formation DfHogas 592 0 kJ molStd Gibbs free energychange of formation DfGogas 545 2 kJ molStandard molar entropy Sogas 325 J mol K Heat capacity cp J mol K Spectral data EditUV VisLambda max nmExtinction coefficient IRMajor absorption bands cm 1NMRPhosphorus 31 NMR 2 2 ppm upfield of H3PO4MSMasses of main fragmentsStructure and properties data EditStructure and propertiesIndex of refraction 1 460Dielectric constant 13 C2 N m2 at 22 CBond strength 533 5 kJ mol P O Bond length 158 pm P O 202 pm P Cl Bond angle 103 Cl P Cl This box viewedit Except where noted otherwise data relate to Standard temperature and pressure Reliability of data general note References Edit Retrieved from https en wikipedia org w index php title Phosphoryl chloride data page amp oldid 1176131413, wikipedia, wiki, book, books, library,

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