The parent compound is ketenimine or CH2CNH. The most recent work by Bane et al. investigates the rovibrational structure of the ν8 and ν12 bands in the high-resolution FTIR spectrum, complementing the earlier analysis of the pure rotational spectrum. This pair of Coriolis coupled bands provide a rare example where intensity sharing between bands yields sufficient intensity for an otherwise invisible band (ν12).[1][2]
Referencesedit
^Michael K. Bane; Christopher D. Thompson; Evan G. Robertson; Dominique R. T. Appadoo; Don McNaughton (2011). "High-resolution FTIR spectroscopy of the ν8 and Coriolis perturbation allowed ν12 bands of ketenimine". Physical Chemistry Chemical Physics. 13 (15): 6793–8. Bibcode:2011PCCP...13.6793B. doi:10.1039/C0CP01816C. PMID 21116541.
^F. J. Lovas; J. M. Hollis; Anthony J. Remijan; P. R. Jewell (2006). "Detection of Ketenimine (CH2CNH) in Sagittarius B2(N) Hot Cores". The Astrophysical Journal. 645 (2): L137–L140. Bibcode:2006ApJ...645L.137L. doi:10.1086/506324.
December 04, 2023
ketenimines, group, organic, compounds, sharing, common, functional, group, with, general, structure, r1r2c, ketenimine, cumulated, alkene, imine, related, allene, ketene, general, structure, keteniminethe, parent, compound, ketenimine, ch2cnh, most, recent, w. Ketenimines are a group of organic compounds sharing a common functional group with the general structure R1R2C C NR3 A ketenimine is a cumulated alkene and imine and is related to an allene and a ketene General structure of a ketenimineThe parent compound is ketenimine or CH2CNH The most recent work by Bane et al investigates the rovibrational structure of the n8 and n12 bands in the high resolution FTIR spectrum complementing the earlier analysis of the pure rotational spectrum This pair of Coriolis coupled bands provide a rare example where intensity sharing between bands yields sufficient intensity for an otherwise invisible band n12 1 2 References edit Michael K Bane Christopher D Thompson Evan G Robertson Dominique R T Appadoo Don McNaughton 2011 High resolution FTIR spectroscopy of the n8 and Coriolis perturbation allowed n12 bands of ketenimine Physical Chemistry Chemical Physics 13 15 6793 8 Bibcode 2011PCCP 13 6793B doi 10 1039 C0CP01816C PMID 21116541 F J Lovas J M Hollis Anthony J Remijan P R Jewell 2006 Detection of Ketenimine CH2CNH in Sagittarius B2 N Hot Cores The Astrophysical Journal 645 2 L137 L140 Bibcode 2006ApJ 645L 137L doi 10 1086 506324 Retrieved from https en wikipedia org w index php title Ketenimines amp oldid 1135328125, wikipedia, wiki, book, books, library,
