Inductive cleavage, in organic chemistry, is the charge-initiated counterpoint to radical initiated alpha-cleavage. Since inductive cleavage does not require unpairing and re-pairing electrons it can occur at both radical cationic and cationic sites.
Mass spectrometryedit
Generally this topic is discussed when covering mass spectrometry and occurs generally by the same mechanisms.[1][2]
To neutralize the positive charge on the ionization site a single two-electron transfer must be made. Neutralization of the positive charge at the ionization site is performed at the expense of the atom adjacent to the ionization site, transferring the positive charge to this atom as a result of the bond cleavage.
Referencesedit
^Todd, J. F. J. (1991). "Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)". Pure and Applied Chemistry. 63 (10): 1541. doi:10.1351/pac199163101541.
inductive, cleavage, organic, chemistry, charge, initiated, counterpoint, radical, initiated, alpha, cleavage, since, inductive, cleavage, does, require, unpairing, pairing, electrons, occur, both, radical, cationic, cationic, sites, mass, spectrometry, editge. Inductive cleavage in organic chemistry is the charge initiated counterpoint to radical initiated alpha cleavage Since inductive cleavage does not require unpairing and re pairing electrons it can occur at both radical cationic and cationic sites Mass spectrometry editGenerally this topic is discussed when covering mass spectrometry and occurs generally by the same mechanisms 1 2 To neutralize the positive charge on the ionization site a single two electron transfer must be made Neutralization of the positive charge at the ionization site is performed at the expense of the atom adjacent to the ionization site transferring the positive charge to this atom as a result of the bond cleavage References edit Todd J F J 1991 Recommendations for nomenclature and symbolism for mass spectroscopy including an appendix of terms used in vacuum technology Recommendations 1991 Pure and Applied Chemistry 63 10 1541 doi 10 1351 pac199163101541 IUPAC Compendium of Chemical Terminology 2nd ed the Gold Book 1997 Online corrected version 2006 a cleavage alpha cleavage doi 10 1351 goldbook A00004 nbsp This article about analytical chemistry is a stub You can help Wikipedia by expanding it vte Retrieved from https en wikipedia org w index php title Inductive cleavage amp oldid 950307639, wikipedia, wiki, book, books, library,
