These were the first organometallic substances prepared; as such, Cadet has been regarded as the father of organometallic chemistry.[2]
This liquid develops white fumes when exposed to air, resulting in a pale flame producing carbon dioxide, water, and arsenic trioxide. It has a nauseating and very disagreeable garlic-like odor.
Around 1840, Robert Bunsen did much work on characterizing the compounds in the liquid and its derivatives. His research was important in the development of radical theory.
Referencesedit
^Seyferth, D. (2001). "Cadet's Fuming Arsenical Liquid and the Cacodyl Compounds of Bunsen". Organometallics. 20 (8): 1488–1498. doi:10.1021/om0101947.
^Jaouen, G. (2006). Bioorganometallics: Biomolecules, Labeling, Medicine. Wiley. ISBN3-527-30990-X.
April 08, 2024
cadet, fuming, liquid, brown, oily, liquid, prepared, 1760, french, chemist, louis, claude, cadet, gassicourt, 1731, 1799, reaction, potassium, acetate, with, arsenic, trioxide, consisted, mostly, dicacodyl, cacodyl, oxide, space, filling, model, dicacodylball. Cadet s fuming liquid was a red brown oily liquid prepared in 1760 by the French chemist Louis Claude Cadet de Gassicourt 1731 1799 by the reaction of potassium acetate with arsenic trioxide 1 It consisted mostly of dicacodyl CH3 2As 2 and cacodyl oxide CH3 2As 2O Space filling model of dicacodylBall and stick model of cacodyl oxideThe global reaction mass balance corresponding to the oxide formation is the following 4 CH3COOK As2O3 CH3 2As 2O 2 K2CO3 2 CO2These were the first organometallic substances prepared as such Cadet has been regarded as the father of organometallic chemistry 2 This liquid develops white fumes when exposed to air resulting in a pale flame producing carbon dioxide water and arsenic trioxide It has a nauseating and very disagreeable garlic like odor Around 1840 Robert Bunsen did much work on characterizing the compounds in the liquid and its derivatives His research was important in the development of radical theory References edit Seyferth D 2001 Cadet s Fuming Arsenical Liquid and the Cacodyl Compounds of Bunsen Organometallics 20 8 1488 1498 doi 10 1021 om0101947 Jaouen G 2006 Bioorganometallics Biomolecules Labeling Medicine Wiley ISBN 3 527 30990 X Retrieved from https en wikipedia org w index php title Cadet 27s fuming liquid amp oldid 1185153823, wikipedia, wiki, book, books, library,
