Alexander E. Shilov (Russian: Шилов, Александр Евгеньевич) (January 1, 1930 – June 6, 2014) was a Russian chemist, one of the leading figures in Physical Organic Chemistry and Catalysis.
Alexander Shilov
Shilov was born in Ivanovo, Russia, studied chemistry in Kiev and received his diploma degree in 1952 from Kiev State University. In 1952-1955 he began working with Nobel Laureate Nikolay Semyonov toward his Ph.D. at the Academy of Sciences in Moscow. After postdoctoral studies with Sir Cyril Norman Hinshelwood at Oxford University in London, he returned to the Institute of Biochemical Physics (Moscow), where he became Director and Professor at Moscow State University. In 1952 he moved to Institute of Problems of Chemical Physics, Russian Academy of Sciences in Chernogolovka (Moscow district), where he became the Head of Laboratory.[1] In 1990 he was elected to the Academy of Scienсes of the USSR, which was in someway equivalent to getting a financial endowment for his research.
Shilov cycle Catalytic cycle for the oxidation of methane to methanol (where R=H) by a Pt(II) complex in the presence of stoichiometric Pt(IV) species as oxidant.
In the late 1960s and early 1970s, he discovered what are considered to be the first reported examples of alkane reactions catalyzed by a homogeneous (solution-phase) system, the Pt-catalyzed CH activation of alkanes,[2][3][4] now known as the Shilov system.[5] Shilov and co-workers conducted extensive mechanistic investigations of this chemistry based on kinetic analysis.[6][7][8][9] In addition to his pioneering work in the activation and functionalization of hydrocarbons, his interests encompassed dinitrogen reduction to ammonia in aqueous media with the use of organometallic complexes.[10]
His work has been published in more than 300 papers which cover research in chemical kinetics and catalysis, mechanisms of chemical reactions, and chemical modeling of enzyme systems.
ReferencesEdit
^A. E. Shilov, G. B. Shul'pin, "Activation of C−H Bonds by Metal Complexes", Chemical Reviews, 1997, 97 (8), pp 2879–2932 https://dx.doi.org/10.1021/cr9411886
^Gol'dshleger, N. F.; Tyabin, M. B.; Shilov, A. E.; Shteinman, A. A. "Activation of saturated hydrocarbons. Deuterium-hydrogen exchange in solutions of transition metal complexes" Zhurnal Fizicheskoi Khimii 1969, 43, 2174-2175
^Gol'dshleger, N. F.; Es'kova, V. V.; Shilov, A. E.; Shteinman, A. A. "Reactions of alkanes in solutions of platinum chloride complexes" Zh. Fiz. Khim. 1972, 46, 1353-13544
^Gol'dshleger, N. F.; Khidekel, M. L.; Shilov, A. E.; Shteinman, A. A. "Oxidative dehydrogenation of saturated hydrocarbons in palladium(II) complex solutions" Kinet. Katal. 1974, 15, 261
^Tyabin, M. B.; Shilov, A. E.; Shteinman, A. A. "Mechanism of platinum-complex catalyzed deuterium-hydrogen exchange involving saturated hydrocarbons and solvent protons" Doklady Akademii Nauk SSSR 1971, 198, 380-383
^Gol'dshleger, N. F.; Es'kova, V. V.; Shilov, A. E.; Shteinman, A. A. "Reactions of alkanes in solutions of platinum chloride complexes" Zh. Fiz. Khim. 1972, 46, 1353-13544
^Muradov, N. Z.; Shilov, A. E.; Shteinman, A. A. "Partial oxidation of simple alkanes" Kinetika i Kataliz 1972, 13, 1357-1358
^Gol'dshleger, N. F.; Khidekel, M. L.; Shilov, A. E.; Shteinman, A. A. "Oxidative dehydrogenation of saturated hydrocarbons in palladium(II) complex solutions" Kinet. Katal. 1974, 15, 261
^Shilov, A. E. Metal Complexes in Biomimetic Chemical Reactions: N2 Fixation in Solution, Activation and Oxidation of Alkanes, Chemical Models of Photosynthesis, 1997
October 19, 2023
alexander, shilov, chemist, confused, with, nikolai, shilov, alexander, shilov, russian, Шилов, Александр, Евгеньевич, january, 1930, june, 2014, russian, chemist, leading, figures, physical, organic, chemistry, catalysis, alexander, shilovshilov, born, ivanov. Not to be confused with Nikolai Shilov Alexander E Shilov Russian Shilov Aleksandr Evgenevich January 1 1930 June 6 2014 was a Russian chemist one of the leading figures in Physical Organic Chemistry and Catalysis Alexander ShilovShilov was born in Ivanovo Russia studied chemistry in Kiev and received his diploma degree in 1952 from Kiev State University In 1952 1955 he began working with Nobel Laureate Nikolay Semyonov toward his Ph D at the Academy of Sciences in Moscow After postdoctoral studies with Sir Cyril Norman Hinshelwood at Oxford University in London he returned to the Institute of Biochemical Physics Moscow where he became Director and Professor at Moscow State University In 1952 he moved to Institute of Problems of Chemical Physics Russian Academy of Sciences in Chernogolovka Moscow district where he became the Head of Laboratory 1 In 1990 he was elected to the Academy of Scienses of the USSR which was in someway equivalent to getting a financial endowment for his research Shilov cycle Catalytic cycle for the oxidation of methane to methanol where R H by a Pt II complex in the presence of stoichiometric Pt IV species as oxidant In the late 1960s and early 1970s he discovered what are considered to be the first reported examples of alkane reactions catalyzed by a homogeneous solution phase system the Pt catalyzed CH activation of alkanes 2 3 4 now known as the Shilov system 5 Shilov and co workers conducted extensive mechanistic investigations of this chemistry based on kinetic analysis 6 7 8 9 In addition to his pioneering work in the activation and functionalization of hydrocarbons his interests encompassed dinitrogen reduction to ammonia in aqueous media with the use of organometallic complexes 10 His work has been published in more than 300 papers which cover research in chemical kinetics and catalysis mechanisms of chemical reactions and chemical modeling of enzyme systems References Edit A E Shilov G B Shul pin Activation of C H Bonds by Metal Complexes Chemical Reviews 1997 97 8 pp 2879 2932 https dx doi org 10 1021 cr9411886 Gol dshleger N F Tyabin M B Shilov A E Shteinman A A Activation of saturated hydrocarbons Deuterium hydrogen exchange in solutions of transition metal complexes Zhurnal Fizicheskoi Khimii 1969 43 2174 2175 Gol dshleger N F Es kova V V Shilov A E Shteinman A A Reactions of alkanes in solutions of platinum chloride complexes Zh Fiz Khim 1972 46 1353 13544 Gol dshleger N F Khidekel M L Shilov A E Shteinman A A Oxidative dehydrogenation of saturated hydrocarbons in palladium II complex solutions Kinet Katal 1974 15 261 Shilov A E Shteinman A A Activation of saturated hydrocarbons by metal complexes in solution Coord Chem Rev 1977 24 97 143 https doi org 10 1016 S0010 8545 00 80336 7 Tyabin M B Shilov A E Shteinman A A Mechanism of platinum complex catalyzed deuterium hydrogen exchange involving saturated hydrocarbons and solvent protons Doklady Akademii Nauk SSSR 1971 198 380 383 Gol dshleger N F Es kova V V Shilov A E Shteinman A A Reactions of alkanes in solutions of platinum chloride complexes Zh Fiz Khim 1972 46 1353 13544 Muradov N Z Shilov A E Shteinman A A Partial oxidation of simple alkanes Kinetika i Kataliz 1972 13 1357 1358 Gol dshleger N F Khidekel M L Shilov A E Shteinman A A Oxidative dehydrogenation of saturated hydrocarbons in palladium II complex solutions Kinet Katal 1974 15 261 Shilov A E Metal Complexes in Biomimetic Chemical Reactions N2 Fixation in Solution Activation and Oxidation of Alkanes Chemical Models of Photosynthesis 1997 Retrieved from https en wikipedia org w index php title Alexander Shilov chemist amp oldid 1162448198, wikipedia, wiki, book, books, library,
